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作者:

Cheng, Jin (Cheng, Jin.) | Han, Shuai (Han, Shuai.) | Ye, Qing (Ye, Qing.) (学者:叶青) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Kang, Tianfang (Kang, Tianfang.) (学者:康天放) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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EI Scopus SCIE

摘要:

Hydrothermal stability of the Cu(A, N, Cl or S)/SAPO.34 samples derived from different Cu precursors (A: Cuacetate; N: Cu-nitrate; Cl: Cu-chloride; and S: Cu-sulfate) was investigated. The physical and chemical properties of the samples were investigated by various analytical techniques, and their catalytic activities for NO conversion and NH3 oxidation were evaluated. The results of NH3-SCR activity show that the Cu(A)/SAPO-34 sample was better than that of the Cu(N, Cl or S)/SAPO-34 sample, which was due to the existence of a less amount of CuO species and a more amount of the isolated Cu2+ species. Moreover, catalytic activities of all aged catalysts decreased in the whole temperature range, which was attributed to the drop in the amount of isolated Cu2+ species in the hydrothermally treated Cu/SAPO-34 samples. After hydrothermal aging treatment, part of the isolated Cu2+ was transformed to CuO, leading to structural instability and deactivation of the catalysts.

关键词:

Copper precursor Cu/SAPO-34 Hydrothermal aging NH3-SCR NO removal Selective catalytic reduction

作者机构:

  • [ 1 ] [Cheng, Jin]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Han, Shuai]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Ye, Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Kang, Tianfang]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn,Lab Catalysis Chem & Nanosc, Key Lab Beijing Reg Air Pollut Control,Beijing Ke, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青 戴洪兴

    [Ye, Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn,Lab Catalysis Chem & Nanosc, Key Lab Beijing Reg Air Pollut Control,Beijing Ke, Beijing 100124, Peoples R China

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来源 :

MICROPOROUS AND MESOPOROUS MATERIALS

ISSN: 1387-1811

年份: 2019

卷: 278

页码: 423-434

5 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:79

JCR分区:1

被引次数:

WoS核心集被引频次: 26

SCOPUS被引频次: 23

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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