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In this paper, based on the relationships of the etch-rate with the feature widths (FWs) from 2μm to 100μm and the results of the etch-rate changing with etch-time for a particular FW, which were obtained by our experiments, a possible etching process model was proposed. When the etch-time was relatively short, it was a reaction limited process. With the etch-time going on, the fresh reactive gas was difficult to diffuse through the etching trench to the fresh reaction interface, the etch-rate decreased, which was called the residual removing limited process. Our mathematic fitting results proved the above etching model and pointed out that for the reaction limited process, the etch depth linearly increase with the etch time. When the etch process was dominated by the residual removing limited process, the etch-rate decreased. © The Electrochemical Society.
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