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摘要:
In this work, we reported a large electrocaloric effect (ECE) in tetragonal perovskite 0.03 Bi(Mg1/2Ti1/2)O-3-0.97 (0.875Bi(1/2)Na(1/2)TiO(3)-0.125BaTiO(3)) ceramic. It was found that the composition demonstrates a coexisting state of the ferroelectric P4mm and relaxor P4bm. Due to the field-induced phase transition from relaxor with P4bm symmetry to ferroelectric with P4mm symmetry, a positive ECE is observed in the temperature range of 25-130 degrees C. Under an electric field of 4 kV/mm, a large temperature change Delta T of 0.75 degrees C was achieved at 80 degrees C, and the EC responsivity Delta T-max/Delta E of 0.19 K.cm/kV, indicating a promising lead-free material for potential application in solid-state refrigerators. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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来源 :
SCRIPTA MATERIALIA
ISSN: 1359-6462
年份: 2019
卷: 162
页码: 256-260
6 . 0 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:211
JCR分区:1