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作者:

Sang, Lixia (Sang, Lixia.) (学者:桑丽霞) | Li, Feng (Li, Feng.) | Xu, Yongwang (Xu, Yongwang.)

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EI Scopus SCIE

摘要:

With the fast development of concentrating solar power, a form-stable composite material containing ternary carbonates (K2CO3-Li2CO3-Na2CO3) as high temperature thermal energy storage materials and ceramic MgO as supporting material is proposed to prevent molten salts from leakage and the relevant corrosion. Using cold compression and mixed sintering method, ternary carbonates can be embedded and distributed uniformly in intervals and pores between MgO particles. There aren't chemical reactions between carbonates and MgO during sintering at a high temperature. Among of samples with different mass ratios, the composite material containing 50 wt% ternary carbonates gives the highest mechanical strength. Specific heat capacity and latent heat of the composite material with an optimal ratio of 5:5 can be up to 1.48 J/g K (450-600 degrees C) and 158.7 kJ/kg, respectively. It has a relative low melting point (386.4 degrees C), and it hasn't obvious mass degradation even at 1000 degrees C due to the strong adsorption of carbonates in intervals and pores between MgO particles. Moreover, the composite material shows a good thermal cycling stability after 100 cycles. The resulting form-stable composite material can provide a wider service temperature range and a higher thermal storage density based on the utilization of latent heat and sensible heat of molten salts.

关键词:

High temperature composite material Ternary carbonates Thermal cycling stability Thermal properties Thermal storage density

作者机构:

  • [ 1 ] [Sang, Lixia]Beijing Univ Technol, Key Lab Enhanced Heat Transfer & Energy Conservat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Sang, Lixia]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Beijing Municipal, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 桑丽霞

    [Sang, Lixia]Beijing Univ Technol, Key Lab Enhanced Heat Transfer & Energy Conservat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

SOLAR ENERGY

ISSN: 0038-092X

年份: 2019

卷: 180

页码: 1-7

6 . 7 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:52

被引次数:

WoS核心集被引频次: 45

SCOPUS被引频次: 49

ESI高被引论文在榜: 0 展开所有

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