A　highly　efficient　and　mild　electrochemical　protocol　has　been　developed　for　the　aza-Michael　addition　of　aromatic　aza-heterocycles　or　Ts-protected　amines　with　alpha,beta-unsaturated　alkenes　to　give　corresponding　beta-amino　sulfone,　beta-amino　nitrile,　beta-amino　ester,　and　beta-amino　ketone　in　moderate　to　excellent　yields.　The　chemistry　proceeded　using　NaI　as　a　redox　mediator　in　an　undivided　cell　at　ambient　temperature.　Unlike　the　conventional　aza-Michael　additions,　the　utilization　of　strong　acid,　base,　or　transition　metal-based　catalysts　is　circumvented.　In　addition,　it　was　observed　the　electrochemically　in　situ-generated　molecular　iodine　has　higher　activity　than　that　under　nonelectrochemical　reaction　conditions.