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作者:

Deng, Shu-hao (Deng, Shu-hao.) | Lu, Hao (Lu, Hao.) | Li, Dongyang (Li, Dongyang.)

收录:

EI Scopus SCIE

摘要:

Effects of ultraviolet (UV) light illumination on the corrosion behavior, surface state, and activities of electro-deposited micro-TiO2/Ni and nano-TiO2/Ni composite foils in 3.5% NaCl solution were investigated by means of polarization measurement, electrochemical impedance spectra (EIS), electron work function mapping (EWF) and XPS spectra analysis using an electrochemical system, the atom force microscopy (AFM) and X-ray photoelectric spectroscopy (XPS), respectively. The UV light illumination resulted in a considerable decrease in corrosion resistance of the nano-TiO2/Ni composite foil but showed much less effect on the micro-TiO2/Ni composite foil. Surface state analysis demonstrated that the UV illumination stimulated the nano-TiO2 semiconductor with elevated conductivity in favor of passing corrosion current. The UV illumination increased the fraction of Ni2O3 component in formed oxide film on the nano-TiO2/Ni foil, which is porous, loose, brittle and less protective, compared to the naturally formed NiO film on Ni. The changes in surface state were responsible for variations in the corrosion behavior of micro-TiO2/Ni and nano-TiO2/Ni composite foils caused by the UV light illumination.

关键词:

Ni TiO2 Corrosion Composite foil Ultraviolet (UV) light illumination

作者机构:

  • [ 1 ] [Deng, Shu-hao]Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China
  • [ 2 ] [Deng, Shu-hao]Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada
  • [ 3 ] [Lu, Hao]Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada
  • [ 4 ] [Li, Dongyang]Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada
  • [ 5 ] [Deng, Shu-hao]Minist Educ, Key Lab Nonferrous Met, Changsha 410083, Hunan, Peoples R China
  • [ 6 ] [Lu, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China

通讯作者信息:

  • [Li, Dongyang]Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada

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来源 :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

年份: 2018

卷: 462

页码: 291-302

6 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:260

JCR分区:1

被引次数:

WoS核心集被引频次: 15

SCOPUS被引频次: 15

ESI高被引论文在榜: 0 展开所有

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