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作者:

Yin, Xiaowen (Yin, Xiaowen.) | Liu, Min (Liu, Min.) | Wan, Baicen (Wan, Baicen.) | Zhang, Yu (Zhang, Yu.) | Liu, Weiqiang (Liu, Weiqiang.) (学者:刘卫强) | Wu, Yufeng (Wu, Yufeng.) (学者:吴玉锋) | Zhang, Dongtao (Zhang, Dongtao.) (学者:张东涛) | Yue, Ming (Yue, Ming.) (学者:岳明)

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摘要:

Environmental friendly recycling process for Nd-Fe-B sintered magnet sludges generated in the manufacturing process, which contain large amount of rare earth, including Nd, Pr and Dy, is badly needed so far. In present study, we have developed an effective route to obtain recycled sintered magnets from Nd-Fe-B sintered magnet sludges by calcium reduction-diffusion (RD) process. Compared to conventional recycling process, our research is focused on recovering most of the useful elements, including Nd, Pr, Dy, Co, and Fe together instead of just rare earth elements. To improve the recycling efficiency and reduce pollution, the co-precipitating parameters were simulated and calculated using MATLAB software. Most of useful elements were recovered by a co-precipitation method, and the obtained composite powders were then directly fabricated as recycled Nd-Fe-B powders by a calcium reduction-diffusion (RD) method. The recovery rates are 98%, 99%, 99%, 93%, and 99%, for Nd, Pr, Dy, Co, and Fe, respectively. The amount of useful elements contained in the recovered composite powders is greater than 99.71 wt%. The process of RD for synthesizing Nd2Fe14B and subsequently removing CaO was thoroughly investigated. Furthermore, the recycled Nd-Fe-B magnet exhibits a remanence of 1.1 T, a coercivity of 1053 kA/m, and an energy product of 235.6 KJ/m(3), respectively, indicating that recycled Nd-Fe-B sintered magnet was successfully recovered from the severely contaminated sludges via an effective recycling route. (C) 2018 Published by Elsevier B.V. on behalf of Chinese Society of Rare Earths.

关键词:

Nd-Fe-B sintered magnet sludges Rare earths Recycled magnet Reduction-diffusion Removing CaO

作者机构:

  • [ 1 ] [Yin, Xiaowen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Min]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wan, Baicen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Yu]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Weiqiang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Dongtao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Yue, Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Wu, Yufeng]Beijing Univ Technol, Inst Circular Econ, Beijing 100124, Peoples R China

通讯作者信息:

  • 岳明

    [Liu, Min]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Yue, Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF RARE EARTHS

ISSN: 1002-0721

年份: 2018

期: 12

卷: 36

页码: 1284-1291

4 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:98

被引次数:

WoS核心集被引频次: 22

SCOPUS被引频次: 24

ESI高被引论文在榜: 0 展开所有

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