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作者:

Tian, J. (Tian, J..) | Zhang, X. (Zhang, X..) | Zhou, Z. (Zhou, Z..) (学者:周正) | Liu, H. (Liu, H..) | Fu, Y. (Fu, Y..) | Zhang, J. (Zhang, J..)

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摘要:

Thermoelectric (TE) materials have received extensive attention for their potential applications in converting various kinds of heat energy into electricity. Bi 2 Te 3 and its alloys are known to be the best TE materials at near room temperature. Bi 2 Te 3 materials own a large power factor and a low thermal conductivity. It is found that the ZT value could be significantly improved by nanocomposite. And one effective way to increase the TE properties is to reduce the thermal conductivity by incorporating nano-sized particles into the matrix. The introduction of the second phase by nano composite can effectively improve the thermoelectric properties of the materials. It is expected that the dispersion of SiC nano-particles in Bi 2 Te 3 could reduce the thermal conductivity but not significantly decrease the electrical conductivity. Bi 2 Te 3 ingots have poor mechanical properties and mechanical alloying (MA) combine the powder sintering process is usually used to improve the mechanical properties of Bi 2 Te 3 -based alloys. N-type nanocomposite Bi 2 (Te 0.9 Se 0.1 ) 3 /(SiC) y (0≤y≤0.02) were fabricated by MA combined with spark plasma sintering (SPS) method using bismuth powder, tellurium powder, selenium powder and nano SiC as raw materials. The effects of nano SiC on phase components, microstructure, and the thermoelectric properties were systematically investigated. The experimental results show that the nanosized SiC particles are dispersed in the grain boundary of Bi 2 (Te 0.9 Se 0.1 ) 3 matrix, the nano composite structure of which can significantly reduce the lattice thermal conductivity and improve the performance of the thermoelectric material. The pattern of electrical transport is n conduction. Meanwhile, with increasing amount of SiC doping, the resistivity and Seebeck coefficient were enhanced, and the samples still have good electrical properties at near the room temperature. Nano SiC can enhance phonon scattering and significantly reduce the thermal conductivity due to its diffuse distribution in grain boundary, which leads to a higher ZT than that of the non-doped samples. The dimensionless figure of merit ZT was improved and reaches maximum value of 0.73 at 323 K for the Bi 2 (Te 0.9 Se 0.1 ) 3 /(SiC) 0.01 sample. © 2018, Chongqing Functional Materials Periodical Press Co. Ltd. All right reserved.

关键词:

Bi 2 Te 3 alloys; Lattice thermal conductivity; SiC nanocomposite; Thermal conductivity; ZT

作者机构:

  • [ 1 ] [Tian, J.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Zhang, X.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Zhou, Z.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Liu, H.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Fu, Y.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Zhang, J.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Zhang, J.]School of Materials Science and Engineering, HeFei University of Technology, Hefei, 230009, China

通讯作者信息:

  • [Zhang, X.]Key Laboratory of Advanced Functional Materials (Ministry of Education), College of Materials Science and Engineering, Beijing University of TechnologyChina

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来源 :

Journal of Functional Materials

ISSN: 1001-9731

年份: 2018

期: 6

卷: 49

页码: 06184-06189

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SCOPUS被引频次: 1

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