• 综合
  • 标题
  • 关键词
  • 摘要
  • 学者
  • 期刊-刊名
  • 期刊-ISSN
  • 会议名称
搜索

作者:

Cheng, Xiaopeng (Cheng, Xiaopeng.) | Li, Yonghe (Li, Yonghe.) | Shi, Huifeng (Shi, Huifeng.) | Lu, Junxia (Lu, Junxia.) | Zhang, Yuefei (Zhang, Yuefei.) (学者:张跃飞)

收录:

EI Scopus SCIE

摘要:

Spinel Co3O4, as conversion-type transitional metal oxide, has attracted extensive interest for LIBs anode due to its high theoretical capacity. The application of transitional metal oxide including Co3O4 anode has been proved challenging due to voltage hysteresis, bad rate capability, extremely low initial Coulombic efficiency (typically 65 similar to 70%), and volume change induced mechanical failure. Among the facing problems, the fundamental understanding of severe capacity fading at high C-rate is clearly needed to be unveiled. In this paper, we utilized in situ transmission electron microscopy (TEM) to study the electrochemical reaction process of spinel Co3O4 anode and firstly unveiled the rate-dependent morphological and structural evolution process. It has been demonstrated that the structural evolution from pristine Co3O4 phase to the formation of Co/Li2O composites during lithiation (bias =similar to 3 V). Impressively, the Co/Li2O composites could fully delithiated into pure tightly-contacted CoO crystals (similar to 1.45 nm) at lower delithiated bias (+3 V); while the lithiated products partially transformed into the CoO crystals, and further suffered a severe aggregation (similar to 6 nm) at higher delithiated bias (+8 V). These findings advance the understanding of the mechanism of capacity fading at high current density (C-rate) in conversion-type spinel Co3O4 anode for lithium ion batteries. (C) 2018 Elsevier B.V. All rights reserved.

关键词:

Cobalt oxide Rate-dependent Transmission electron microscopy Conversion Anode

作者机构:

  • [ 1 ] [Cheng, Xiaopeng]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yonghe]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Shi, Huifeng]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Yuefei]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Lu, Junxia]Beijing Univ Technol, Inst Laser Engn, Beijing 100022, Peoples R China

通讯作者信息:

  • 张跃飞

    [Zhang, Yuefei]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China;;[Lu, Junxia]Beijing Univ Technol, Inst Laser Engn, Beijing 100022, Peoples R China

查看成果更多字段

相关关键词:

来源 :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

年份: 2018

卷: 763

页码: 349-354

6 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:260

JCR分区:1

被引次数:

WoS核心集被引频次: 7

SCOPUS被引频次: 7

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 1

在线人数/总访问数:237/4783074
地址:北京工业大学图书馆(北京市朝阳区平乐园100号 邮编:100124) 联系我们:010-67392185
版权所有:北京工业大学图书馆 站点建设与维护:北京爱琴海乐之技术有限公司