Molybdenum　disulfide　(MoS2)　is　one　of　the　most　important　solid　lubricants　used　in　titanium　(Ti)　to　reduce　the　friction　coefficient.　The　adherent　capability　between　MoS2　and　Ti　determines　its　application.　A　layer　of　titanium　dioxide　nanotube　(TNT)　array　film　had　been　prepared　to　strengthen　the　binding　force　between　the　solid　lubricant　and　Ti　substrate.　The　existence　of　the　TNT　increases　the　strength　of　the　basement　and　provide　a　solid　support　for　MoS2　nanosheets.　The　tribology　test　reveals　that　the　new　structure　of　Ti/TNT/MoS2　exhibits　extremely　stable　performance.　Dramatic　improvement　in　combining　capability　(471　x　)　at　low　friction　coefficient　(0.11)　was　realized　compared　with　Ti/MoS2　structure,　suggesting　the　promising　application　in　friction　and　wear　field,　for　example,　Ti　fasteners　used　in　aerospace.