A　new　approach　was　developed　to　load　4,4＇-bis-methylene　cyclohexane　diisocyanate　in　microcapsules,　with　outstanding　stability　in　thermal　and　chemical　environments,　and　excellent　efficiency　for　both　self-healing　and　self-lubricating　uses.　Well-dispersed　microcapsules　with　diameter　of　80　+/-　22　mu　m　and　shell　thickness　of　3.8　+/-　0.2　mu　m　were　produced　with　a　core　fraction　of　74　+/-　1.3　wt%　as　determined　by　titration.　In　thermal　environments,　the　microcapsules　started　to　lose　5%　mass　at　230　degrees　C,　which　was　higher　than　the　boiling　point　of　pure　HMDI　and　thermal　decomposition　temperature　of　shell　material.　In　chemical　environments　(hexane,　xylene,　ethyl　acetate　and　water),　the　impermeable　microcapsules　reserved　more　than　90%　of　original　core　material　after　20　days　immersion.　More　interestingly,　final　microcapsules　survived　successfully　in　acetone　losing　only　25%　of　core　material　after　24　h.　Parameters　including　microcapsules　size,　concentrations,　immersion　durations　and　solvent　polarity　were　investigated　systematically　to　obtain　the　stability　of　microcapsules　in　organic　solvents.　The　smart　coatings　(10　wt%　microcapsules)　showed　outstanding　self-healing　anticorrosion　efficiency　in　sodium　chloride　solutions,　and　their　friction　coefficient　decreased　by　80%　than　control　samples.