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作者:

Xu, Peng (Xu, Peng.) | Zhang, Xing (Zhang, Xing.) | Zhao, Xingtian (Zhao, Xingtian.) | Yang, Jun (Yang, Jun.) | Hou, Zhiquan (Hou, Zhiquan.) | Bai, Lu (Bai, Lu.) | Chang, Huaiqiu (Chang, Huaiqiu.) | Liu, Yuxi (Liu, Yuxi.) | Deng, Jiguang (Deng, Jiguang.) | Guo, Guangsheng (Guo, Guangsheng.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴) | Au, Chak-Tong (Au, Chak-Tong.)

收录:

EI Scopus SCIE

摘要:

Three-dimensionally ordered macroporus LaMnAl11O19 (3DOM LMAO) and its supported Pd, Pd-Pt, and Pt nanoparticles were prepared using the polymethyl methacrylate-templating and polyvinyl alcohol-protected reduction methods, respectively. The 1100 degrees C-calcined 3DOM LMAO support possessed a hexaaluminate phase, and its supported noble metal samples displayed a high surface area of 26-29 m(2)/g. A Pd-Pt alloy was generated in the PdPt/3DOM LMAO samples, and the particle sizes of the noble metal nanoparticles (NPs) were 3-5 nm. The 0.97 wt% Pd/3DOM LMAO (0.97 P d/3DOM LMAO) sample possessed the highest surface adsorbed oxygen concentration and the best low-temperature reducibility, showing the highest catalytic activity (T-10% = 259 degrees C, T-50% = 308 degrees C, and T-90% = 343 degrees C at SV = 20,000 mL/(g h)) for methane combustion. The 1.14 wt% Pd2.8Pt/3DOM LMAO (1.14Pd(2.8)Pt/3DOM LMAO) sample performed the best (T-10% = 284 degrees C, T-50% = 372 degrees C, and T-90% = 456 degrees C at SV = 20,000 mL/(g h)) among the PdPt/3DOM LMAO samples. Doping of Pt to the Pd-based catalyst could improve the H2O-, CO2-, and SO2-resistant ability without significant influence on thermal stability, although 1.14Pd(2.8)Pt/3DOM LMAO was less active than 0.97 P d/3DOM LMAO for methane combustion. The ex situ X-ray photoelectron spectroscopy was used to explore the formation of active PdO species during the oxidation processes of Pd in 1.14Pd(2.8)Pt/3DOM LMAO and 0.97Pd/3DOM LaMnAl11O19 at different temperatures.

关键词:

Bimetallic nanoparticle Ex situ XPS Methane combustion Supported noble metal catalyst Three-dimensionally ordered macropore

作者机构:

  • [ 1 ] [Xu, Peng]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Xing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 3 ] [Zhao, Xingtian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [Yang, Jun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Hou, Zhiquan]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Yuxi]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 7 ] [Deng, Jiguang]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 8 ] [Guo, Guangsheng]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 9 ] [Dai, Hongxing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 10 ] [Xu, Peng]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 11 ] [Zhang, Xing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 12 ] [Zhao, Xingtian]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 13 ] [Yang, Jun]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 14 ] [Hou, Zhiquan]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 15 ] [Liu, Yuxi]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 16 ] [Deng, Jiguang]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 17 ] [Guo, Guangsheng]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 18 ] [Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 19 ] [Xu, Peng]Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
  • [ 20 ] [Bai, Lu]Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
  • [ 21 ] [Chang, Huaiqiu]Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
  • [ 22 ] [Au, Chak-Tong]Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

通讯作者信息:

  • 戴洪兴

    [Guo, Guangsheng]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Guo, Guangsheng]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China;;[Au, Chak-Tong]Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

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来源 :

APPLIED CATALYSIS A-GENERAL

ISSN: 0926-860X

年份: 2018

卷: 562

页码: 284-293

5 . 5 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:98

JCR分区:1

被引次数:

WoS核心集被引频次: 14

SCOPUS被引频次: 17

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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