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作者:

Shi, Xiao-Lei (Shi, Xiao-Lei.) | Zheng, Kun (Zheng, Kun.) (学者:郑坤) | Liu, Wei-Di (Liu, Wei-Di.) | Wang, Yuan (Wang, Yuan.) | Yang, Yu-Zhe (Yang, Yu-Zhe.) | Chen, Zhi-Gang (Chen, Zhi-Gang.) | Zou, Jin (Zou, Jin.)

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EI Scopus SCIE

摘要:

In this study, a record high figure of merit (ZT) of approximate to 1.1 at 773 K is reported in n-type highly distorted Sb-doped SnSe microplates via a facile solvothermal method. The pellets sintered from the Sb-doped SnSe microplates show a high power factor of approximate to 2.4 mu W cm(-1) K-2 and an ultralow thermal conductivity of approximate to 0.17 W m(-1) K-1 at 773 K, leading a record high ZT. Such a high power factor is attributed to a high electron concentration of 3.94 x 10(19) cm(-3) via Sb-enabled electron doping, and the ultralow thermal conductivity derives from the enhanced phonon scattering at intensive crystal defects, including severe lattice distortions, dislocations, and lattice bent, observed by detailed structural characterizations. This study fills in the gaps of fundamental doping mechanisms of Sb in SnSe system, and provides a new perspective to achieve high thermoelectric performance in n-type polycrystalline SnSe.

关键词:

n-type doping thermoelectric materials solvothermal synthesis tin selenide thermal conductivity

作者机构:

  • [ 1 ] [Shi, Xiao-Lei]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia
  • [ 2 ] [Liu, Wei-Di]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia
  • [ 3 ] [Yang, Yu-Zhe]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia
  • [ 4 ] [Chen, Zhi-Gang]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia
  • [ 5 ] [Zou, Jin]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia
  • [ 6 ] [Zheng, Kun]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100022, Peoples R China
  • [ 7 ] [Wang, Yuan]Univ Southern Queensland, Ctr Future Mat, Springfield, Qld 4300, Australia
  • [ 8 ] [Chen, Zhi-Gang]Univ Southern Queensland, Ctr Future Mat, Springfield, Qld 4300, Australia
  • [ 9 ] [Zou, Jin]Univ Queensland, Ctr Microscopy & Microanal, Brisbane, Qld 4072, Australia

通讯作者信息:

  • [Chen, Zhi-Gang]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia;;[Zou, Jin]Univ Queensland, Mat Engn, Brisbane, Qld 4072, Australia;;[Chen, Zhi-Gang]Univ Southern Queensland, Ctr Future Mat, Springfield, Qld 4300, Australia;;[Zou, Jin]Univ Queensland, Ctr Microscopy & Microanal, Brisbane, Qld 4072, Australia

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来源 :

ADVANCED ENERGY MATERIALS

ISSN: 1614-6832

年份: 2018

期: 21

卷: 8

2 7 . 8 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:260

JCR分区:1

被引次数:

WoS核心集被引频次: 129

SCOPUS被引频次: 132

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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