A　sulfonic　acid　functionalized　metal-organic　framework　(MOF)　Cr-3(mu　O-3)(H2O)(3)(NDC(SO3H5/6)(2))(3)　(BUT-8(Cr)-SO3H,　NDC(SO3H)(2)(2-)　=　4,8-disulfonaphthalene-2,6-dicarboxylatlate)　with　high　chemical　and　thermal　stability　is　used　for　the　catalytic　esterification,　showing　excellent　performanceinm　vrinous　esterification　reactions　of　monoacids,　diacids,　and　acid　anhydrides.　In　the　structure　of　this　MOF,　uniformly　distributed　catalytic　active　sites　of　Bronsted　acidic　-SO3H　with　high　density　are　decorated　on　its　one-dimensional　channels,　which　leads　to　improved　catalytic　activity.　The　reaction　conversion　and　corresponding　yield　of　esters　can　achieve　＞99%　and　＞90%,　respectively.　BUT-8(Cr)-SO3H　also　represents　good　size-selectivity　in　the　catalytic　esterification　owning　to　the　strinc　or　impeded　diffusion　effects　of　reactantsinm　its　pore　structure.　In　addition,　its　robust　structure　also　guarantees　good　reusability.　On　the　basis　of　the　above　advantages　and　excellent　catalytic　performance,　this　acid　group　functionalized　MOF　could　be　a　promising　candidate　for　the　sustainable　chemical　catalysis.