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Author:

Wang, B. B. (Wang, B. B..) | Qu, X. L. (Qu, X. L..) | Zhu, M. K. (Zhu, M. K..) | Levchenko, I. (Levchenko, I..) | Baranov, O. (Baranov, O..) | Zhong, X. X. (Zhong, X. X..) | Xu, S. (Xu, S..) (Scholars:徐硕) | Ostrikov, K. (Ostrikov, K..)

Indexed by:

EI Scopus SCIE

Abstract:

Highly controllable structural transformation of various doped carbon and boron nitride nanomaterials have been achieved with the perspective of their application in microelectronics, optoelectronics, energy devices and catalytic reactions. Specifically, the syntheses of one-dimensional (1D) boron and nitrogen co-doped tube-like carbon nanorods and 2D vertical carbon and oxygen co-doped boron nitride nanosheets on silicon coated with gold films in N-2-H-2 plasma was demonstrated. During the synthesis of nanomaterials, boron carbide was used as carbon and boron sources. The results of characterizations by scanning and transmission electron microscopes, as well as micro-Raman and X-ray photoelectron spectroscopes indicate that the formation of different nanomaterials relates to the growth temperature and quantity of boron carbide. Specifically, 1D tube-like carbon nanorods doped with boron and nitrogen are formed at similar to 910 degrees C using a small quantity of boron carbide, while 2D vertical boron nitride nanosheets doped with carbon and oxygen are grown at similar to 870 degrees C using a large quantity of boron carbide. These studies indicate that the behaviors of a reactive intermediate product B2O3 on surfaces of Au nanoparticles play an important role in the formation of different nanomaterials, i.e., whether the B2O3 molecules deposited on Au nanoparticles are desorbed mainly determines the formation of different nanomaterials. The formation of 2D vertical carbon and oxygen co-doped boron nitride nanosheets is related to the high growth rate of edges of nanosheets. Furthermore, the photoluminescence (PL) properties of 1D boron and nitrogen co-doped tube-like carbon nanorods and 2D vertical carbon and oxygen co-doped boron nitride nanosheets were studied at room temperature. The PL results show that all the nanomaterials generate the ultraviolet, blue, green and red PL bands, but the 2D vertical carbon and oxygen co-doped boron nitride nanosheets emit more and stronger PL bands than the 1D boron and nitrogen co-doped tubelike carbon nanorods. The significant differences in the PL properties can be attributed to different carbon structures in these nanomaterials. These achievements can be used to synthesize and control the structures of nanomaterials and contribute to the development of the next generation optoelectronic nanodevices based on 1D and 2D nanomaterials. (C) 2018 Elsevier B.V. All rights reserved.

Keyword:

Behaviors of intermediate product B2O3 Boron and nitrogen co-doped tube-like carbon nanorods Chemical vapor deposition Photoluminescence Carbon and oxygen co-doped boron nitride nanosheets

Author Community:

  • [ 1 ] [Wang, B. B.]Chongqing Univ Technol, Coll Chem & Chem Engn, 69 Hongguang Rd, Chongqing 400054, Peoples R China
  • [ 2 ] [Qu, X. L.]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Zhu, M. K.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Levchenko, I.]Nanyang Technol Univ, Natl Inst Educ, Plasma Sources & Applicat Ctr, 1 Nanyang Walks, Singapore 637616, Singapore
  • [ 5 ] [Xu, S.]Nanyang Technol Univ, Natl Inst Educ, Plasma Sources & Applicat Ctr, 1 Nanyang Walks, Singapore 637616, Singapore
  • [ 6 ] [Levchenko, I.]Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4000, Australia
  • [ 7 ] [Ostrikov, K.]Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4000, Australia
  • [ 8 ] [Baranov, O.]Natl Aerosp Univ, Kharkov, Ukraine
  • [ 9 ] [Zhong, X. X.]Shanghai Jiao Tong Univ, Dept Phys & Astron, Shanghai 200240, Peoples R China
  • [ 10 ] [Ostrikov, K.]CSIRO QUT Joint Sustainable Proc & Devices Lab, POB 218, Lindfield, NSW 2070, Australia

Reprint Author's Address:

  • [Wang, B. B.]Chongqing Univ Technol, Coll Chem & Chem Engn, 69 Hongguang Rd, Chongqing 400054, Peoples R China

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Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2018

Volume: 442

Page: 682-692

6 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:260

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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