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作者:

Yang Jing-Jie (Yang Jing-Jie.) | Zhao Jin-Liang (Zhao Jin-Liang.) | Xu Lei (Xu Lei.) | Zhang Hong-Guo (Zhang Hong-Guo.) | Yue Ming (Yue Ming.) (学者:岳明) | Liu Dan-Min (Liu Dan-Min.) (学者:刘丹敏) | Jiang Yi-Jian (Jiang Yi-Jian.) (学者:蒋毅坚)

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EI Scopus SCIE PKU CSCD

摘要:

Magnetic refrigeration materials based on magnetocaloric effect (MCE) attract wide attention. In the past decades, magnetic materials with MCE have been extensively studied due to their enormous potential applications in magnetic refrigeration fields. Among these materials, La(Fe, Al)(13) compound is perceived to be one of the promising candidates as high-performance magnetic refrigerant because of its giant magnetic entropy change, tunable Curie temperature, low cost and toxin-free. For LaFe13-xAlx compounds, previous studies showed that the T-C can increase by substituting Co for Fe, which leads to the value of maximum magnetic entropy change (-Delta S-M) decreasing. In addition, the interstitial atom (N, H, C and B) can cause the lattice to expand, which shifts the anti-ferromagnetic (AFM) ground state to the ferromagnetic (FM) state. The T-C increases with doping the interstitial atoms, accompanied by a remarkable change in the magnetic properties related to the magneto-volume effect. In this paper, the magnetic properties and the magnetocaloric effects of LaFe11.Al-5(1).H-5(x) (x = -0, 0.12, 0.6 and 1.3), LaFe11.5Al1.5By (y = 0.1, 0.2 and 0.3) and LaFe11.5Al1.5Cz (z = 0.1, 0.2, 0.3, 0.4 and 0.5) intermetallic compounds are studied. The H, B or C atoms are inserted into the LaFe11.5Al1.5 compounds by gas-solid or solid-solid reaction. All the compounds crystallize into the cubic NaZn13-type structure. The magnetic ground state changes from the AFM to the FM state due to the introduction of interstitial atoms. Unlike the patent compound LaFe11.5Al1.5, all of the hydrides, borides and carbides display a typical FM state, which easily reach saturation under a magnetic field of 1 T. In addition, the saturation magnetization (M-S) slightly increases and the Curie temperature (T-C) significantly is enhanced with increasing the interstitial atom (H, B or C) content. It is attractive that the magnetic transition changes from the second-order to the weakly first-order with increasing hydrogen content, which is in contrast with the magnetic transition from the weakly first-order to the second-order with increasing boron or carbon content. All the compounds of LaFe11.5Al1.5 hydrides, borides and carbides exhibit a considerable magnetic entropy change. The values of maximum magnetic entropy change (-Delta S-M) reach 12.3 J/kg.K for LaFe11.5Al1.5H1.3, 9.6 J/kg.K for LaFe11.5Al1.5B0.1 and 10.8 J/kg.K for LaFe11.5Al1.5C0.2 under a magnetic field change of 0-5 T, respectively. And the values of refrigerant capacity (RC) reach 259.2 J/kg for LaFe11.5Al1.5H0.6, 116.4 J/kg for LaFe11.5Al1.5B0.1, and 230.4 J/kg for LaFe11.5Al1.5C0.1 under a magnetic field change of 0-5 T, respectively, indicating that LaFe11.5Al1.5H0.6 compound is a promising candidate for magnetic refrigerants.

关键词:

La(Fe, Al)(13) compounds interstitial atom phase transition magnetocaloric effect

作者机构:

  • [ 1 ] [Yang Jing-Jie]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Zhao Jin-Liang]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Xu Lei]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Xu Lei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Hong-Guo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Liu Dan-Min]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 8 ] [Jiang Yi-Jian]Beijing Univ Technol, Inst Laser Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 岳明

    [Zhao Jin-Liang]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China;;[Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

ACTA PHYSICA SINICA

ISSN: 1000-3290

年份: 2018

期: 7

卷: 67

1 . 0 0 0

JCR@2022

ESI学科: PHYSICS;

ESI高被引阀值:145

JCR分区:4

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 1

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