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WC-12Co composite powder was synthesized by reduction and carburization reactions. With adding various contents of combined grain growth inhibitors (GGI) VC and Cr3C2 into the WC-12Co composite powder, the effects of the GGI addition on the phase constitution, microstructure and mechanical properties of the WC-12Co coating prepared by HVOF were investigated by X-ray diffraction (XRD) arid scanning electron microscopy (SEM). The results show that with the content of GGI increasing in the composite powder, the abnormal grain growth disappears, homogeneous ultrafine grain structure forms, and the coefficient of friction of the coating declines. When the total amount of inhibitor is 1.0 wt%, the maximum hardness (HV0.3) of WC-12Co coating is 13 670 MPa, and the wear rate of the coating is the lowest. With further increasing the content of inhibitor, the wear rate of the coating increases, while the hardness and the wear resistance of the coating decrease.
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