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摘要:
In this study, we report the effect of Zn doping on the thermoelectric properties of Co1-x Zn (x) SbS0.85Se0.15 solid solutions (x = 0, 0.02, 0.05, 0.08). The results show the dimensionless figure of merit (zT) increases from 0.17 to 0.34 at 875 K for Co0.95Zn0.05SbS0.85Se0.15 sample, due to the noticeable decrease in the lattice thermal conductivity by introducing point defect, which is further confirmed by an analysis based on the Debye-Callaway-Klemens model. Meanwhile, the thermoelectric power factor is maintained at high temperatures. This work highlights the important role of point defect in improving the thermoelectric performance of CoSbS-based compounds.
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来源 :
RARE METALS
ISSN: 1001-0521
年份: 2018
期: 4
卷: 37
页码: 326-332
8 . 8 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:260
JCR分区:3
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