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作者:

Sang, Lixia (Sang, Lixia.) (学者:桑丽霞) | Zhao, Yangbo (Zhao, Yangbo.) | Niu, Youchen (Niu, Youchen.) | Bai, Guangmei (Bai, Guangmei.)

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摘要:

TiO2 with Nanoring/Nanotube (R/T) hierarchical structure can be prepared by tuning the oxidation time and oxidation voltage in the second step anodization. The resulting multiabsorption oscillating peaks in the visible light region present a strong dependence on the tube length which are derived from the interference of light reflected from the top nanorings and the bottom Ti substrate, and the optical path length in TiO2 R/T hierarchical structure can be estimated as about 2 mu m. The tube length of the as-prepared TiO2 photoelectrode affects greatly its saturation photocurrent density, and the different tube-wall thickness can change the photocurrent-saturation potential. Under simulated AM 1.5 irradiation (100 mW/cm(2)), TiO2 R/T hierarchical structure with tube diameters of 20-40 nm and tube length of about 1.5 mu m shows higher photocurrent density and hydrogen production rate at the bias of 0 V (vs. Ag/AgCl). The results from the IPCE plots and I-t curves verify that TiO2 R/T hierarchical structure can exhibit the visible light activity, which is more related to the absorption induced by the defects rather than oscillating peaks. Based on the unique multiple light reflection in TiO2 R/T hierarchical structure, surface treatment will pave a way for the better utilization of oscillating peaks in the visible light region. (C) 2017 Elsevier B.V. All rights reserved.

关键词:

Hydrogen production Nanoring/nanotube hierarchical structure Oscillating peaks Photoelectrochemical properties TiO2

作者机构:

  • [ 1 ] [Sang, Lixia]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 2 ] [Sang, Lixia]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China

通讯作者信息:

  • 桑丽霞

    [Sang, Lixia]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China

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来源 :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

年份: 2018

卷: 430

页码: 496-504

6 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:131

JCR分区:1

被引次数:

WoS核心集被引频次: 9

SCOPUS被引频次: 9

ESI高被引论文在榜: 0 展开所有

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