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作者:

Xie, W. (Xie, W..) | Tang, Z. (Tang, Z..) | Fu, H. (Fu, H..) | Zou, C. (Zou, C..) | Kuang, J. (Kuang, J..) | Deng, Y. (Deng, Y..)

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摘要:

In order to study the alkaline leaching process of the boron ore further, the boron bearing tailings from Kuandian calcined at 700℃ were treated as the raw material in this article, on the basis of the shrinking core model, the kinetic equation of alkaline hydrolysis reaction in NaOH solution for boron of ore samples was deduced, and the alkaline hydrolysis experiment was conducted on the raw material, the kinetic equation theoretically deduced was fit and validated according to the experiment results. The research shows that the alkaline hydrolysis reaction process of boron under the experimental conditions coincide well with the shrinking core model, the kinetic equation of boron in the alkaline hydrolysis reaction process is t=42.4954[(1-X)-1/3+1/3ln(1-X)-1]+0.0338[(1-X)-2/3-1], the kinetic process of it is mainly controlled by diffusion mechanism, elevating the temperature of solution, increasing the concentration of NaOH solution and reducing the particle size of ore samples are conducive to shorten the alkaline hydrolysis time and complete the reaction as soon as possible. The kinetics establishes a preliminary theoretical foundation for the alkaline treatment application of the boron ore. © 2016, Materials Review Magazine. All right reserved.

关键词:

Alkaline hydrolysis reaction; Boron bearing tailings; Diffusion control; Kinetics; Shrinking core model

作者机构:

  • [ 1 ] [Xie, W.]Hunan Province Key Laboratory of Safety Design and Reliability Technology for Engineering Vehicle, Changsha University of Science and Technology, Changsha, 410114, China
  • [ 2 ] [Tang, Z.]Key Laboratory of Lightweight and Reliability Technology for Engineering Vehicle, The Education Department of Hunan Province, Changsha University of Science and Technology, Changsha, 410114, China
  • [ 3 ] [Fu, H.]College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Zou, C.]Hunan Province Key Laboratory of Safety Design and Reliability Technology for Engineering Vehicle, Changsha University of Science and Technology, Changsha, 410114, China
  • [ 5 ] [Kuang, J.]Key Laboratory of Lightweight and Reliability Technology for Engineering Vehicle, The Education Department of Hunan Province, Changsha University of Science and Technology, Changsha, 410114, China
  • [ 6 ] [Deng, Y.]Hunan Province Key Laboratory of Safety Design and Reliability Technology for Engineering Vehicle, Changsha University of Science and Technology, Changsha, 410114, China

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来源 :

Materials Review

ISSN: 1005-023X

年份: 2016

期: 6

卷: 30

页码: 158-162

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SCOPUS被引频次: 2

ESI高被引论文在榜: 0 展开所有

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