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The removal efficiency of effluent organic matter (EfOM) by ozonation was investigated. Ultrafiltration separation and fluorescence excitation-emission matrix spectroscopy were used to study the effect of ozone dosage on the variation in EfOM's molecular weight distribution, hydrophobicity-hydrophilicity, and fluorescence characteristics. The results revealed that ozonation had a limited effect on the removal of EfOM, but it could effectively oxidize organic compounds with strong UV absorption. Ozonation could also decompose high molecule organic matter and improve the biodegradability of EfOM. During ozonation, the organic matter with MW>100 kDa was completely decomposed, the content of organic matter with 10 kDa<MW<100 kDa and 1 kDa<MW<10 kDa also declined, and the content of organic matter with MW<1 kDa increased steadily as the oxidation time rose. After ozonation, the hydrophilic components in EfOM increased, while the hydrophobic components and the acidic components decreased. The fluorescent intensities of protein-like and humic-like substances in EfOM declined rapidly as the ozone dosage increased. © 2016, Science Press. All right reserved.
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