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The performance of wastewater ozonation treatment could be improved when microbubble technology was applied. The pH value is a crucial factor for ozonation treatment. The microbubble ozonation treatment of acid red 3R wastewater was investigated under different initial pH. The results indicated the significant influence of pH on ozone decomposition in microbubble ozonation. The ozone decomposition under strong acid and alkaline conditions was faster than that under neutral condition. The decoloration rate and TOC removal rate in microbubble ozonation treatment of acid red 3R wastewater could be accelerated significantly under acid and alkaline conditions, compared with these under neutral condition. The TOC removal efficiency could reach up to 83.1% under acid condition and its TOC removal rate was about twice as high as that under neutral condition. In addition, the ratios of TOC removed to ozone consumed under acid, alkaline and neutral conditions were 0.0372, 0.0298 and 0.0180 mg/mg, respectively. These indicated that the strongest oxidative activity in microbubble ozonation could be achieved under acid condition. The ozone utilization efficiencies were higher than 99% in the microbubble ozonation treatment under different initial pH. © 2016, Science Press. All right reserved.
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