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作者:

Fan, Xing (Fan, Xing.) | Kang, Sijing (Kang, Sijing.) | Li, Jian (Li, Jian.) | Zhu, Tianle (Zhu, Tianle.)

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摘要:

A coaxial dielectric barrier discharge (DBD) reactor has been developed for plasma and plasma-catalytic conversion of dilute N2O in N-2 and N-2-O-2 mixtures at both room and high temperature (300 degrees C). The effects of catalyst introduction, O-2 content and inlet N2O concentration on N2O conversion and the mechanism involved in the conversion of N2O have been investigated. The results show that N2O in N-2 could be effectively decomposed to N-2 and O-2 by plasma and plasma-catalytic processes at both room and high temperature, with much higher decomposition efficiency at 300 degrees C than at room temperature for the same discharge power. Under an N-2-O-2 atmosphere, however, N2O could be removed only at high temperature, producing not only N-2 and O-2 but also NO and NO2. Production and conversion of N2O occur simultaneously during the plasma and plasma-catalytic processing of N2O in a N-2-O-2 mixture, with production and conversion being the dominant processes at room and high temperature, respectively. N2O conversion increases with the increase of discharge power and decreases with the increase of O-2 content. Increasing the inlet N2O concentration from 100 to 400 ppm decreases the conversion of N2O under an N-2 atmosphere but increases that under an N-2-O-2 atmosphere. Concentrating N2O in the N-2-O-2 mixture could alleviate the negative influence of O-2 by increasing the involvement of plasma reactive species (e.g., N-2(A(3)Sigma(+)(u)) and O(D-1)) in N2O conversion. Packing the discharge zone with a RuO2/Al2O3 catalyst significantly enhances the conversion of N2O and improves the selectivity of N2O decomposition under an N-2-O-2 atmosphere, revealing the synergy of plasma and catalyst in promoting N2O conversion, especially its decomposition to N-2 and O-2.

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作者机构:

  • [ 1 ] [Fan, Xing]Beijing Univ Technol, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Kang, Sijing]Beijing Univ Technol, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Jian]Beijing Univ Technol, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Zhu, Tianle]Beihang Univ, Sch Space & Environm, Beijing 100191, Peoples R China

通讯作者信息:

  • [Fan, Xing]Beijing Univ Technol, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

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来源 :

RSC ADVANCES

ISSN: 2046-2069

年份: 2018

期: 47

卷: 8

页码: 26998-27007

3 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:192

被引次数:

WoS核心集被引频次: 26

SCOPUS被引频次: 24

ESI高被引论文在榜: 0 展开所有

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