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The reaction behavior of C6H6 was investigated in a tubular-flow reactor containing a three-way catalyst. Experiments were performed to investigate the effects of coexistence gas components, temperature, gas flow rate and operating age of catalytic converter. The components of C6H6, H2, CO, H2O, HC, O2 and N2 were selected from the gasoline engine exhaust gas. The experimental results show that the oxidation of C6H6 was enhanced by the presence of O2 and CO, while the presences of H2, HC and H2O have suppressive effect on the oxidation of C6H6 than O2 and CO. The results reveal that catalyst has lower catalytic oxidation activity for C6H6 oxidation at lower temperature, and has higher catalytic oxidation activity for C6H6 than CH4, C2H6 and C3H8, and decomposition of C6H6 via catalyst was similar to the decompositions of C2H4 and C3H6. The operating age of catalytic converter has lower effect on the oxidation of C6H6 with an increase in the operating time of catalytic converter from 0 to 80,000km. © 2014, International Journal of GEOMATE.
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