Synthesis and crystal structure of tetra-copper (I) complex with n-heterocyclic thioether ligand - 文章详情页

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摘要：

A　novel　Cu(I)　complex　[Cu4I4L2]　[L=2-methylpyridyl　pyrimidyl　sulfide]　has　been　synthesized　through　solution　diffusion　method　and　characterized　by　single　crystal　X-ray　diffraction　and　IR　spectrum.　The　title　complex　crystallizes　in　monoclinic　crystal　system　with　P21/n　space　group　with　a=1.004　70(5)　nm,　b=0.893　04(4)　nm,　c=1.815　98(8)　nm,　β=99.847(10)°,　V=1.605　36(13)　nm3,　Z=2,　and　Mr=1　196.40.　The　tetra-nuclear　structure　is　composed　of　the　molecule　[Cu4I4L2]　and　its　three-dimensional　nets　are　constructed　ultimately　by　supra-molecule　weak　interactions　including　hydrogen　bond,　S⋯S　and　π-π　interaction.

关键词：

Crystal structure; Cu (I) complex; N-heterocyclic thioether

作者机构：

[ 1 ] [Xie, Y.-B.]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
[ 2 ] [Wang, L.]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
[ 3 ] [Zhou, Y.-Y.]State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
[ 4 ] [Zhang, C.-Y.]State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
[ 5 ] [Gao, Q.]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
[ 6 ] [Wang, H.-H.]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

通讯作者信息：

谢亚勃
[Xie, Y.-B.]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

电子邮件地址：

xieyabo@bjut.edu.cn

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