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作者:

Tian, Y.-L. (Tian, Y.-L..) | Cheng, J.-S. (Cheng, J.-S..) | Zhu, M.-K. (Zhu, M.-K..) | Guo, X.-L. (Guo, X.-L..) | Sun, S.-B. (Sun, S.-B..) (学者:孙诗兵) | Shao, Y.-L. (Shao, Y.-L..) | Zhang, J. (Zhang, J..)

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摘要:

High temperature resistivity of high alkali aluminoilicate glasses at 600-1 625°C is investigated in this paper. Experimental results show that the resistivity of glass melts increases with the K2O/Na2O ratio in an temperature range of 900-1 625°C. The temperature dependence agrees well with the Arrhenius law, which implies that the resistivity of the glass melt is controlled by ion migration. The investigation of the temperature dependent resistivity of high alkali aluminosilicate glasses show that the electric conductivity behavior of glass has a transition near 900°C, which indicates that the aggregation degree of glass network structure and the binding force of modifier ions have an effect on glass electrical resistivity, and the diffusion of alkali metal ions attributes to the electric conductivity above 900°C, the activation energy is between 50-65 kJ/mol; while the glass conductivity capacity is poor at 600-900°C, which is controlled by migration mechanisms of alkali metal ions, and the activation energy is 100-120 kJ/mol.

关键词:

Conductance activation energy; High alkali aluminosilicate glasses; High temperature resistance

作者机构:

  • [ 1 ] [Tian, Y.-L.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Tian, Y.-L.]School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
  • [ 3 ] [Cheng, J.-S.]School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
  • [ 4 ] [Zhu, M.-K.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 5 ] [Guo, X.-L.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 6 ] [Sun, S.-B.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 7 ] [Shao, Y.-L.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 8 ] [Zhang, J.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

通讯作者信息:

  • [Tian, Y.-L.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

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来源 :

Journal of Beijing University of Technology

ISSN: 0254-0037

年份: 2014

期: 1

卷: 40

页码: 127-130

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