Advanced　cathode　catalysts　are　crucial　to　the　promotion　of　aprotic　Li-O-2　batteries　for　practical　applications.　Carbon　is　usually　used　as　a　cathode　catalyst,　but　it　reacts　with　the　discharge　products　(Li2O2,　LiO2)　to　form　an　insulating　layer　of　lithium　carbonate　and　prevents　further　reaction.　To　resolve　this　issue,　the　development　of　non-carbon　cathode　catalysts　is　of　great　demand.　Herein,　for　the　first　time,　we　designed　and　fabricated　a　MnCo2O4　(MCO)　spinel　oxide　decorated　Magneli　phase　Ti4O7　as　a　carbon-free　cathode　for　Li-O-2　batteries.　The　sub-stoichiometric　Ti4O7　oxide　serves　as　an　electronic　conductive　network.　The　MCO　spinel　oxide　along　with　the　synergistic　effect　between　Ti4O7　and　MCO　facilitate　the　kinetics　of　both　oxygen　reduction　and　decomposition　of　Li2O2.　Furthermore,　uniform　anchoring　of　MCO　nanoparticles　on　Ti4O7　surface　provides　a　stable　lithium　peroxide-cathode　interface　during　the　discharge/charge　process.　The　resulting　Ti4O7/MCO　hybrid　proves　to　be　a　highly　effective　cathode　catalyst.　The　discharge/charge　voltage　gap　of　the　Ti4O7/MCO　hybrid　is　about　0.75　V,　which　is　significantly　lower　than　that　of　pure　carbon,　C　+　MCO　and　pristine　Ti4O7　cathode.　A　high　specific　capacity　(5400　mA　h　g(-1)　at　100　mA　g(-1))　and　excellent　cycling　performance　(100　cycles　at　a　capacity　of　500　mA　h　g(-1)　under　200　mA　g(-1))　were　obtained　for　this　hybrid.　The　high　catalytic　activity　and　durability　renders　the　Ti4O7/MCO　hybrid　a　highly　promising　carbon-free　cathode　for　Li-O-2　batteries.