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The addition of scandium oxide to dispenser cathodes (namely Scandate cathodes), which are typically comprised of a porous tungsten matrix impregnated with Ba-Ca-aluminate, improves the emission by a factor of tens to hundreds under the same operating temperature. The fabrication, emission property and emission mechanism of Scandate cathodes have been reviewed. Four types were summarized in this paper: the traditional impregnated Scandate cathode, "top-layer" impregnated Scandate cathode, impregnated mixed matrix Scandate cathode and pressed Scandate cathode. It was found that decreasing the grain size from micrometer to sub-micrometer could enhance the cathode emission performance. Mixed matrix Scandate cathode prepared with scandium oxide doped tungsten powder which has the characteristic of superfine Sc2O3 particles dispersing uniformly over and among sub-micrometer W grains, might be the main type of Scandate cathodes in the future. The emission models for explaining the conspicuous emission performance were summarized. Although the operating mechanism of Scandate cathodes is still unclear, it is accepted that the emission is correlated with a surface multilayer/monolayer of Ba-Sc-O. The layer is formed after proper activation by diffusion of free or ionic Sc together with Ba and O from the interior of the cathode to its surface. The correlation between the emission properties of scandate cathodes and their surface features has been established. © 2011 Nova Science Publishers, Inc.
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