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作者:

Dou, Yibo (Dou, Yibo.) | Zhou, Jian (Zhou, Jian.) (学者:周剑) | Zhou, Awu (Zhou, Awu.) | Li, Jian-Rong (Li, Jian-Rong.) (学者:李建荣) | Nie, Zuoren (Nie, Zuoren.) (学者:聂祚仁)

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EI Scopus SCIE

摘要:

A strategy that visible-light responsive zeolitic-imidazolate-framework-67 ( ZIF-67) encapsulates noblemetal sensitized semiconductors, ZnO@M ( M = Au, Pt, and Ag) to fabricate composite catalysts for photoelectrochemical (PEC) water splitting is proposed. The obtained ZnO@M@ZIF-67 catalysts have good catalytic performance, particularly, the ZnO@Au@ZIF-67 exhibits quite improved photoconversion efficiency and photocurrent density, superior to most of the reported photoelectrode catalysts. This can be attributed to the wider solar spectra harvesting capability originating from visible-light responsive ZIF67 and UV-light active ZnO. Simultaneously, their integration enables interfacial electrons in the ZIF-67 shell to easily transfer to the ZnO@Au core, providing good electron-hole separation. In addition, the porous ZIF-67 as a protective shell ensures structural robustness, while maintaining fast ion or gas bubble diffusion through its pores, accounting for stable and excellent PEC performance.

关键词:

作者机构:

  • [ 1 ] [Dou, Yibo]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Jian-Rong]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Dou, Yibo]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Zhou, Jian]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 6 ] [Zhou, Awu]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 7 ] [Li, Jian-Rong]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

通讯作者信息:

  • 李建荣 聂祚仁

    [Li, Jian-Rong]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China;;[Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF MATERIALS CHEMISTRY A

ISSN: 2050-7488

年份: 2017

期: 36

卷: 5

页码: 19491-19498

1 1 . 9 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:287

中科院分区:1

被引次数:

WoS核心集被引频次: 100

SCOPUS被引频次: 110

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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