Graphene　(Gr)/polymeric　pyrrole-sodium　dodecyl　benzene　sulfonate　(PPy-SDBS)　were　used　to　modify　the　palladium　loaded　titanium　electrode.　The　palladium/graphene/polymeric　pyrrole-sodium　dodecyl　benzene　sulfonate/titanium　(Pd/Gr/PPy-SDBS/Ti)　electrode　was　successfully　prepared　by　the　simple　drop-casting/electrodeposition　process.　The　Pd/Gr/PPy-SDBS/Ti　electrode　showed　high　electrochemical　activity　in　the　application　of　the　electrochemically　reductive　dechlorination　of　2,4,6-trichlorophenol　(2,4,6-TCP)　in　aqueous　solution.　The　influence　factors　of　dechlorination　including　dechlorination　current　and　initial　pH　value　were　studied　and　the　optimum　dechlorination　current　and　initial　pH　value　within　the　investigated　range　were　5　mA　and　2.3,　respectively.　Under　these　conditions,　100　mg　L-1　2,4,6-TCP　could　be　removed　and　dechlorinated　completely　within　80　min,　and　the　current　efficiency　could　reach　36%.　The　main　final　product　of　2,4,6-TCP　was　phenol　and　the　dechlorination　pathways　were　studied　according　to　the　intermediate　products　detected　by　HPLC.　The　dechlorination　reaction　of　2,4,6-TCP　fitted　well　to　the　pseudo-first-order　kinetics.　The　effect　of　temperature　on　2,4,6-TCP　dechlorination　and　the　stability　of　the　prepared　electrode　were　also　investigated.