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作者:

Zhang, Li-Fang (Zhang, Li-Fang.) | Ke, Xiaoxing (Ke, Xiaoxing.) | Ou, Gang (Ou, Gang.) | Wei, Hehe (Wei, Hehe.) | Wang, Lu-Ning (Wang, Lu-Ning.) | Wu, Hui (Wu, Hui.)

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EI Scopus SCIE CSCD

摘要:

Molybdenum disulfide (MoS2) has attracted extensive attention as an alternative to replace noble electro-catalysts in the hydrogen evolution reaction (HER). Here, we highlight an efficient and straightforward ball milling method, using nanoscale Cu powders as reductant to reduce MoS2 engineering S-vacancies into MoS2 surfaces, to fabricate a defect-rich MoS2 material (DR-MoS2). The micron-sized DR-MoS2 catalysts exhibit significantly enhanced catalytic activity for HER with an overpotential (at 10 mA cm(-2)) of 176 mV in acidic media and 189 mV in basic media, surpassing most of Mo-based catalysts previously reported, especially in basic solution. Meanwhile stability tests confirm the outstanding durability of DR-MoS2 catalysts in both acid and basic electrolytes. This work not only opens a new pathway to implant defects to MoS2, but also provides low-cost alternative for efficient electrocatalytic production of hydrogen in both alkaline and acidic environments.

关键词:

defects hydrogen evolution electrocatalyst MoS2 S-vacancies

作者机构:

  • [ 1 ] [Zhang, Li-Fang]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 2 ] [Wang, Lu-Ning]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 3 ] [Zhang, Li-Fang]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 4 ] [Ou, Gang]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 5 ] [Wei, Hehe]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 6 ] [Wu, Hui]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 7 ] [Ke, Xiaoxing]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

通讯作者信息:

  • [Wang, Lu-Ning]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China;;[Wu, Hui]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China

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来源 :

SCIENCE CHINA-MATERIALS

ISSN: 2095-8226

年份: 2017

期: 9

卷: 60

页码: 849-856

8 . 1 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:287

中科院分区:3

被引次数:

WoS核心集被引频次: 29

SCOPUS被引频次: 27

ESI高被引论文在榜: 0 展开所有

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