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作者:

Zhou, Na (Zhou, Na.) | Du, Wen-Bo (Du, Wen-Bo.) (学者:杜文博) | Zhang, Pei-Long (Zhang, Pei-Long.) | Zhu, Yong-Guo (Zhu, Yong-Guo.) | Wang, Zhao-Hui (Wang, Zhao-Hui.) | Liu, Ke (Liu, Ke.) (学者:刘克) | Li, Shu-Bo (Li, Shu-Bo.)

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Scopus SCIE CSCD

摘要:

The present study aims to improve electrochemical properties of the La-Mg-Ni-based hydrogen storage alloys through partial substitution for La by mischmetal (MM). The La0.8-xMMxMg0.2Ni3.1Co0.3Al0.1 (x = 0, 0.1, 0.2, 0.3) alloys were prepared by inductive melting, and their phase structures and electrochemical properties were studied by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectrometry (EDX) and electrochemical tests. Results show that the alloys mainly consist of La2Ni7-type phase, La5Ni19-type phase, LaNi5-type phase and LaNi3-type phase. The addition of MM does not change the phase compositions, while it leads to more uniform phase distribution and obviously promotes the formation of La2Ni7-type phase which possesses favorable electrochemical properties. Electrochemical studies indicate that the substitution for La by MM could effectively improve the high rate dischargeability (HRD) of the alloy electrode, and the optimal value of HRD1500 (HRD at 1500 mA.g(-1)) increases from 40.63 % (x = 0) to 60.55 % (x = 0.3). Although the activation properties of the alloy electrodes keep almost unchanged, both the maximum discharge capacity (C-max) and the cycling stability are significantly improved by MM addition.

关键词:

Cycling stability Microstructure High rate dischargeability Hydrogen storage alloy Discharge capacity

作者机构:

  • [ 1 ] [Zhou, Na]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Du, Wen-Bo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Zhao-Hui]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Liu, Ke]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Shu-Bo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Pei-Long]Whole Win Mat Sci & Technol Co Ltd, Beijing 100083, Peoples R China
  • [ 7 ] [Zhu, Yong-Guo]Whole Win Mat Sci & Technol Co Ltd, Beijing 100083, Peoples R China

通讯作者信息:

  • 杜文博

    [Du, Wen-Bo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

RARE METALS

ISSN: 1001-0521

年份: 2017

期: 8

卷: 36

页码: 645-650

8 . 8 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:287

中科院分区:3

被引次数:

WoS核心集被引频次: 2

SCOPUS被引频次: 2

ESI高被引论文在榜: 0 展开所有

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