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A series of powder samples Ba3Y1-x-y(PO4)(3):xTm(3+)-yDy(3+) were synthesized by a standard solid state reaction. The structure of the compound was confirmed by XRD technique. The concentration quenching of Ba3Y1-x-y (PO4)(3):xTm(3+) was investigated in detail. The photoluminescence emission and decay measurements of Ba3Y1-x-y (PO4)(3):kTm(3+)-yDy(3+) revealed the energy transfer from Tm3+ to Dy3+ ions under 359 nm excitation. The energy transfer mechanism from Tm3+ to Dy3+ in Ba3Y1-x-y(PO4)(3):xTm(3+) -yDy(3+) phosphors was confirmed. The emitting colors could be tuned form blue to white and then to yellow through adjusting the concentration of Tm3+/Dy3+ ions. Under 353 nm excitation, the corresponding color coordinates of the Ba3Y0.93(PO4)(3):0.03Tm(3+) -0.04Dy(3+) phosphors is very close to the stand white color chromaticity coordinates (x=0.33, y=0.33).
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