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摘要:
A new porphyrinic metal-organic framework (MOF), [Co(DCDPP)]center dot 5H(2)O, was designed and constructed by using a bifunctional ligand, 5,15-di(4-carboxylphenyl)-10,20-di(4-pyridyl) porphyrin (H2DCDPP). This MOF features a three-dimensional framework structure with open channels, surrounded by high-density non-coordinating carboxylic groups, and exhibits a high proton conductivity of 3.9 x 10(-2) S cm(-1) at 80 degrees C and 97% relative humidity, higher than most conductive MOFs. Moreover, it also shows excellent stability in boiling water and cyclic proton conduction.
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来源 :
JOURNAL OF MATERIALS CHEMISTRY A
ISSN: 2050-7488
年份: 2017
期: 28
卷: 5
页码: 14525-14529
1 1 . 9 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:287
中科院分区:1