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作者:

Wu, Hao (Wu, Hao.) | Yang, Fan (Yang, Fan.) | Lv, Xiu-Liang (Lv, Xiu-Liang.) | Wang, Bin (Wang, Bin.) | Zhang, Yong-Zheng (Zhang, Yong-Zheng.) | Zhao, Min-Jian (Zhao, Min-Jian.) | Li, Jian-Rong (Li, Jian-Rong.) (学者:李建荣)

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EI Scopus SCIE

摘要:

A new porphyrinic metal-organic framework (MOF), [Co(DCDPP)]center dot 5H(2)O, was designed and constructed by using a bifunctional ligand, 5,15-di(4-carboxylphenyl)-10,20-di(4-pyridyl) porphyrin (H2DCDPP). This MOF features a three-dimensional framework structure with open channels, surrounded by high-density non-coordinating carboxylic groups, and exhibits a high proton conductivity of 3.9 x 10(-2) S cm(-1) at 80 degrees C and 97% relative humidity, higher than most conductive MOFs. Moreover, it also shows excellent stability in boiling water and cyclic proton conduction.

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作者机构:

  • [ 1 ] [Zhao, Min-Jian]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Zhao, Min-Jian]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Jian-Rong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Jian-Rong]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 李建荣

    [Zhao, Min-Jian]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Li, Jian-Rong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF MATERIALS CHEMISTRY A

ISSN: 2050-7488

年份: 2017

期: 28

卷: 5

页码: 14525-14529

1 1 . 9 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:287

中科院分区:1

被引次数:

WoS核心集被引频次: 118

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ESI高被引论文在榜: 0 展开所有

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