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A series of Cu45Zr42Al8Ag5 amorphous rods with 3 mm in diameter were prepared by isothermal treatment in supercooled liquid. The effect of isothermal treatment in supercooled liquid on the thermal stability and mechanical properties of Cu-based bulk metallic glasses were studied. The results showed that the samples were composites containing in situ crystalline after supercooling treatment, and exhibited an excellent thermal stability. From the compressive stress-elongation curves of Cu45Zr42Al8Ag5 BMG alloys, the compressive fracture strength gradually decreased with the increase of holding time, as the compressive plastic strain increased. And the best compressive strength and plastic strain were 2266 MPa and 1.46%, respectively. Compared to the samples fabricated by overheating treatment, samples prepared by supercooling treatment exhibited better mechanical properties. The fracture surface of the sample treated at 1090 K for 6 min showed obviously vein-like patterns, which was contributed to the high compressive fracture strength of Cu-based bulk amorphous alloys.
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