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作者:

Liu, F. (Liu, F..) | Hou, B. (Hou, B..) | Yue, M. (Yue, M..) (学者:岳明) | Wang, K. (Wang, K..)

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摘要:

The magnetic properties of bulk nanocrystalline metal gadolinium (Gd) and dysprosium (Dy) samples were studied. The magnetization and Curie temperature TC of nanocrystalline Gd and Dy decreased usually as compared with the polycrystal. However, when the mean grain size was 10 nm, the Curie temperature TC of nanocrystalline Dy increased to 100 K instead and there was an antiferromagnetic phase in nanocrystalline Gd. According to the calculation based on Ruderman-Kittel-Kasuya-Yosida exchange interaction, the exchange integral of the grain boundary atoms and crystalline surface atoms had its sign changed from plus to minus or vice versa, and there were three orderly phases in the steady state with the lowest energy, ferromagnetic phase, antiferromagnetic phase and fan phase. For the nanocrystals with mean grain size of 10 nm, the proportion of grain boundary to crystalline surface atoms was high, and as the result of superposition of the three phases, and there appeared a peak near the phase transition temperature for the nanocrystalline Gd. While for the Dy, the magnetization decreased gently with temperature, and showing a higher Curie temperature than in the case of the polycrystal.

关键词:

Fan phase; Gd and Dy; Heavy rare earth metal; Magnetic phase transition; Nanocrystal

作者机构:

  • [ 1 ] [Liu, F.]College of Applied Science, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Hou, B.]College of Applied Science, Beijing University of Technology, Beijing 100124, China
  • [ 3 ] [Yue, M.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 4 ] [Wang, K.]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

通讯作者信息:

  • [Hou, B.]College of Applied Science, Beijing University of Technology, Beijing 100124, China

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来源 :

Journal of the Chinese Rare Earth Society

ISSN: 1000-4343

年份: 2011

期: 1

卷: 29

页码: 36-40

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