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0.2Pb(Zn1/3Nb2/3)O3-0.8 Pb(Zr0.5Ti0.5)O3 (0.2PZN-0.8PZT) ceramics were prepared by conventional mixed oxide method, and the effect of Ag doping on the microstructure and electric properties of 0.2PZN-0.8PZT was investigated in detail. The results revealed that the solubility limit of Ag+ in perovskite lattice was near 0.1%. Below the solubility limit, Ag+ entered A site of ABO3 structure to replace Pb2+, and played as doping role to influence the electric properties. While at high doping level above the solubility limit, the excess Ag accumulated at grain boundaries as the form of pure Ag particles, which were homogenously dispersed in the 0.2PZN-0.8PZT matrix. The Ag particles induced the inner stress during the cooling stage after sintering, resulting in the transformation of domain structure and the variation of the resistivity and piezoelectric properties.
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