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摘要:
In this paper, we study the effects of Pr substitution on the hydrogenating process and magnetocaloric properties of La1-x PrxFe11.4Si1.6Hy hydrides. The powder x-ray diffraction patterns of the La1-x PrxFe11.4Si1.6 and its hydrides show that each of the alloys is crystallized into the single phase of cubic NaZn13-type structure. There are hydrogen-absorbing plateaus under 0.4938 MPa and 0.4882 MPa in the absorbing curves for the La-0.8 Pr0.2Fe11.4Si1.6 and La0.6Pr0.4Fe11.4Si1.6 compounds. The releasing processes lag behind the absorbing process, which is obviously different from the coincidence between absorbing and releasing curves of the LaFe11.4Si1.6 compound. The remnant hydrogen content for La0.6Pr0.4Fe11.4Si1.6 is significantly more than that for La0.8Pr0.2Fe11.4Si1.6 after hydrogen desorption, indicating that more substitutions of Pr for La are beneficial to retaining more hydrogen atoms in the alloys. The values of maximum magnetic entropy change are 14.91 J/kg center dot K and 17.995 J/kg center dot K for La0.8Pr0.2Fe11.4 si(1.6)H(0.13) and La0.6Pr0.4Fe11.4Si1.6 H-0.87, respectively.
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来源 :
CHINESE PHYSICS B
ISSN: 1674-1056
年份: 2017
期: 6
卷: 26
1 . 7 0 0
JCR@2022
ESI学科: PHYSICS;
ESI高被引阀值:158
中科院分区:4