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In this paper, hydrogen peroxide catalytic wet oxidation was used to treat leachate from refuse transfer station. Several effects on the catalytic wet oxidation were studied. Three-dimensional excitation-emission matrix (3DEEM) fluorescence spectroscopy and UV-Vis spectroscopy were used to characterize the change of dissolved organic matter (DOM) for the pre and post catalytic wet oxidation treatment. The results showed that under the optimal conditions, COD removal rate could reach more than 90%; and the spectroscopic analysis results showed that the hydrogen peroxide catalytic wet oxidation had significant effect on the degradation of the DOM in the leachates. DOMs containing aromatic nucleus and the conjugate double bond and carbonyl conjugate could be removed effectively. ©, 2015, Science Press. All right reserved.
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