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作者:

Li, Xiangyu (Li, Xiangyu.) | Liu, Yuxi (Liu, Yuxi.) | Deng, Jiguang (Deng, Jiguang.) | Xie, Shaohua (Xie, Shaohua.) | Zhao, Xingtian (Zhao, Xingtian.) | Zhang, Yang (Zhang, Yang.) | Zhang, Kunfeng (Zhang, Kunfeng.) | Arandiyan, Hamidreza (Arandiyan, Hamidreza.) | Guo, Guangsheng (Guo, Guangsheng.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

收录:

EI Scopus SCIE

摘要:

Three-dimensionally ordered macroporous (3DOM) CoFe2O4, zMnO(x)/3DOM CoFe2O4 (z =4.99-12.30 wt%), and yPd-Pt/6.70 wt% MnOx/3DOM CoFe2O4 (y = 0.44-1.81 wt%; Pd/Pt molar ratio = 2.1-2.2) have been prepared using the polymethyl methacrylate microspheres-templating, incipient wetness impregnation, and bubble-assisted polyvinyl alcohol-protected reduction strategies, respectively. All of the samples were characterized by means of various techniques. Catalytic performance of the samples was measured for methane combustion. It is shown that the as-prepared samples exhibited a high-quality 3DOM structure (103 +/- 20 nm in pore size) and a surface area of 19-28 m(2)/g, and the noble metal or alloy nanoparticles (NPs) with a size of 2.2-3.0 nm were uniformly dispersed on the macropore wall surface of 3DOM CoFe2O4. The loading of MnOx on CoFe2O4 gave rise to a slight increase in activity, however, the dispersion of Pd-Pt NPs on 6.70MnO(x)/3DOM CoFe2O4 significantly enhanced the catalytic performance, with the 1.81Pd(2.1) Pt/6.70MnO(x)/3DOM CoFe2O4 sample showing the highest activity (T-10% = 255 degrees C, T-50% = 301 degrees C, and T-90% = 372 degrees C at a space velocity of 20,000 mL/(g h)). We believe that the excellent catalytic activity of 1.81Pd(2.1) Pt/6.70MnO(x)/3 DOM CoFe2O4 was related to its well-dispersed Pd-Pt alloy NPs, high adsorbed oxygen species concentration, good low-temperature reducibility, and strong interaction between MnOx or Pd-Pt NPs and 3DOM CoFe2O4. (C) 2017 Elsevier B.V. All rights reserved.

关键词:

Cobalt ferrate Methane combustion Supported manganese oxide catalyst Supported noble metal nanoparticle Three-dimensionally ordered macropore

作者机构:

  • [ 1 ] [Li, Xiangyu]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Yuxi]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 3 ] [Deng, Jiguang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 4 ] [Xie, Shaohua]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 5 ] [Zhao, Xingtian]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Yang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Kunfeng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 8 ] [Guo, Guangsheng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 9 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 10 ] [Arandiyan, Hamidreza]Univ New South Wales, Sch Chem Engn, Particles & Catalysis Res Grp, Sydney, NSW 2052, Australia

通讯作者信息:

  • 戴洪兴

    [Guo, Guangsheng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China

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来源 :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

年份: 2017

卷: 403

页码: 590-600

6 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:169

中科院分区:1

被引次数:

WoS核心集被引频次: 44

SCOPUS被引频次: 46

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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