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Author:

Li, Xiangyu (Li, Xiangyu.) | Liu, Yuxi (Liu, Yuxi.) | Deng, Jiguang (Deng, Jiguang.) | Xie, Shaohua (Xie, Shaohua.) | Zhao, Xingtian (Zhao, Xingtian.) | Zhang, Yang (Zhang, Yang.) | Zhang, Kunfeng (Zhang, Kunfeng.) | Arandiyan, Hamidreza (Arandiyan, Hamidreza.) | Guo, Guangsheng (Guo, Guangsheng.) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

EI Scopus SCIE

Abstract:

Three-dimensionally ordered macroporous (3DOM) CoFe2O4, zMnO(x)/3DOM CoFe2O4 (z =4.99-12.30 wt%), and yPd-Pt/6.70 wt% MnOx/3DOM CoFe2O4 (y = 0.44-1.81 wt%; Pd/Pt molar ratio = 2.1-2.2) have been prepared using the polymethyl methacrylate microspheres-templating, incipient wetness impregnation, and bubble-assisted polyvinyl alcohol-protected reduction strategies, respectively. All of the samples were characterized by means of various techniques. Catalytic performance of the samples was measured for methane combustion. It is shown that the as-prepared samples exhibited a high-quality 3DOM structure (103 +/- 20 nm in pore size) and a surface area of 19-28 m(2)/g, and the noble metal or alloy nanoparticles (NPs) with a size of 2.2-3.0 nm were uniformly dispersed on the macropore wall surface of 3DOM CoFe2O4. The loading of MnOx on CoFe2O4 gave rise to a slight increase in activity, however, the dispersion of Pd-Pt NPs on 6.70MnO(x)/3DOM CoFe2O4 significantly enhanced the catalytic performance, with the 1.81Pd(2.1) Pt/6.70MnO(x)/3DOM CoFe2O4 sample showing the highest activity (T-10% = 255 degrees C, T-50% = 301 degrees C, and T-90% = 372 degrees C at a space velocity of 20,000 mL/(g h)). We believe that the excellent catalytic activity of 1.81Pd(2.1) Pt/6.70MnO(x)/3 DOM CoFe2O4 was related to its well-dispersed Pd-Pt alloy NPs, high adsorbed oxygen species concentration, good low-temperature reducibility, and strong interaction between MnOx or Pd-Pt NPs and 3DOM CoFe2O4. (C) 2017 Elsevier B.V. All rights reserved.

Keyword:

Three-dimensionally ordered macropore Supported noble metal nanoparticle Cobalt ferrate Methane combustion Supported manganese oxide catalyst

Author Community:

  • [ 1 ] [Li, Xiangyu]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Yuxi]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 3 ] [Deng, Jiguang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 4 ] [Xie, Shaohua]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 5 ] [Zhao, Xingtian]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Yang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Kunfeng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 8 ] [Guo, Guangsheng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 9 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China
  • [ 10 ] [Arandiyan, Hamidreza]Univ New South Wales, Sch Chem Engn, Particles & Catalysis Res Grp, Sydney, NSW 2052, Australia

Reprint Author's Address:

  • 戴洪兴

    [Guo, Guangsheng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat,Coll En, Key Lab Beijing Reg Air Pollut Control,Dept Chem, Key Lab Adv Funct Mat,Educ Minist China,Lab Catal, Beijing 100124, Peoples R China

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Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2017

Volume: 403

Page: 590-600

6 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:287

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 45

SCOPUS Cited Count: 49

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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