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作者:

Gong, Hongyu (Gong, Hongyu.) | Cao, Xuecheng (Cao, Xuecheng.) | Li, Fan (Li, Fan.) (学者:李钒) | Gong, Yue (Gong, Yue.) | Gu, Lin (Gu, Lin.) | Mendes, Rafael Gregorio (Mendes, Rafael Gregorio.) | Rummeli, Mark H. (Rummeli, Mark H..) | Strasser, Peter (Strasser, Peter.) | Yang, Ruizhi (Yang, Ruizhi.)

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摘要:

During start-up and shut-down operations of fuel cells, high potential is inevitably experienced at cathode, which leads to the deterioration of the oxygen reduction electrocatalyst. The design of catalysts that can repair themselves under severe conditions has been identified as a primary challenge for fuel cells. Herein, self-supported PdAuCu branched nanostructure is synthesized by a hydrothermal method. By smartly utilizing the high-potential treatment, the activity of PdAuCu is significantly enhanced owing to the synergistic effect between the Pd and Cu-II generated by such treatment. Moreover, the high activity of PdAuCu can be well maintained by repeating the high-potential treatment. We hence propose this catalyst as a self-repairing catalyst in a broad sense.

关键词:

self-repair electrocatalyst synergistic effect oxygen reduction reaction palladium

作者机构:

  • [ 1 ] [Gong, Hongyu]Soochow Univ, Ctr Suzhou Nano Sci & Technol, Coll Phys Optoelect & Energy & Collaborat Innovat, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Jiangsu, Peoples R China
  • [ 2 ] [Cao, Xuecheng]Soochow Univ, Ctr Suzhou Nano Sci & Technol, Coll Phys Optoelect & Energy & Collaborat Innovat, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Jiangsu, Peoples R China
  • [ 3 ] [Mendes, Rafael Gregorio]Soochow Univ, Ctr Suzhou Nano Sci & Technol, Coll Phys Optoelect & Energy & Collaborat Innovat, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Jiangsu, Peoples R China
  • [ 4 ] [Rummeli, Mark H.]Soochow Univ, Ctr Suzhou Nano Sci & Technol, Coll Phys Optoelect & Energy & Collaborat Innovat, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Jiangsu, Peoples R China
  • [ 5 ] [Yang, Ruizhi]Soochow Univ, Ctr Suzhou Nano Sci & Technol, Coll Phys Optoelect & Energy & Collaborat Innovat, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Jiangsu, Peoples R China
  • [ 6 ] [Li, Fan]Beijing Univ Technol, Sch Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 7 ] [Gong, Yue]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 8 ] [Gu, Lin]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 9 ] [Mendes, Rafael Gregorio]IFW Dresden, Helmholtz Str 20, D-01069 Dresden, Germany
  • [ 10 ] [Rummeli, Mark H.]IFW Dresden, Helmholtz Str 20, D-01069 Dresden, Germany
  • [ 11 ] [Rummeli, Mark H.]Polish Acad Sci, Ctr Polymer & Carbon Mat, M Curie Sklodowskiej 34, PL-41819 Zabrze, Poland
  • [ 12 ] [Strasser, Peter]Tech Univ Berlin, Dept Chem, Chem Engn Div, D-10623 Berlin, Germany

通讯作者信息:

  • [Yang, Ruizhi]Soochow Univ, Ctr Suzhou Nano Sci & Technol, Coll Phys Optoelect & Energy & Collaborat Innovat, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Jiangsu, Peoples R China

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来源 :

CHEMSUSCHEM

ISSN: 1864-5631

年份: 2017

期: 7

卷: 10

页码: 1469-1474

8 . 4 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:212

中科院分区:1

被引次数:

WoS核心集被引频次: 19

SCOPUS被引频次: 20

ESI高被引论文在榜: 0 展开所有

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