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作者:

Zhang, Tiejun (Zhang, Tiejun.) | Li, Jian (Li, Jian.) (学者:李坚) | He, Hong (He, Hong.) (学者:何洪) | Song, Qianqian (Song, Qianqian.) | Liang, Quanming (Liang, Quanming.)

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EI Scopus SCIE CSCD

摘要:

A series of Co-La catalysts were prepared using the wet impregnation method and the synthesis of catalysts were modified by controlling pH with the addition of ammonium hydroxide or oxalic solution. All the catalysts were systematically investigated for NO oxidation and SO2 resistance in a fixed bed reactor and were characterized by Brunanuer-Emmett-Teller (BET) method, Fourier Transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Thermogravimetric (TG) and Ion Chromatography (IC). Among the catalysts, the one synthesized at pH = 1 exhibited the maximum NO conversion of 43% at 180 degrees C. The activity of the catalyst was significantly suppressed by the existence of SO2 (300 ppm) at 220 degrees C. Deactivation may have been associated with the generation of cobalt sulfate, and the SO2 adsorption quantity of the catalyst might also have effected sulfur resistance. In the case of the compact selective catalytic reduction (SCR), the activity increased from 74% to 91% at the highest gas hourly space velocity (GHSV) of 300000 h(-1) when the NO catalyst maintained the highest activity, in excess of 50% more than that of the standard SCR. (C) Higher Education Press and Springer-Verlag Berlin Heidelberg 2016

关键词:

High space velocity Low temperature NO catalytic oxidation pH effect SCR Sulfur dioxide

作者机构:

  • [ 1 ] [Zhang, Tiejun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Jian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [He, Hong]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Song, Qianqian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Liang, Quanming]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Jian]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 7 ] [He, Hong]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

通讯作者信息:

  • 李坚

    [Li, Jian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Li, Jian]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

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来源 :

FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING

ISSN: 2095-2201

年份: 2017

期: 2

卷: 11

6 . 4 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:120

中科院分区:4

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 6

ESI高被引论文在榜: 0 展开所有

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