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摘要:
Transparent and blue ZnO:Ga (GZO) single crystals have been grown by the traveling-solvent floating-zone technique using the solvent B2O3 + MoO3 + Nb2O5. The crystals were typically 9-14 mm in diameter and 46-120 mm in length. The largest one was phi 12 mm x 120 mm in size. All GZO crystals were grown along the < 001 > direction. The growth rate was 0.3-0.5 mm/h, which was far faster than 0.1 mm/day of that grown by the hydrothermal method. The crystalline quality has been characterized by single crystal X-ray diffraction and X-ray rocking curve measurements. Ga substituted on Zn-site and was saturated at about 0.5 wt % of Ga2O3 addition. The GZO crystal doped with 0.5 wt % Ga2O3 has the lowest electrical resistivity of 1.083 x 10(-3) Omega cm and the highest carrier concentration of 1.78 x 10(20) cm(-3). [GRAPHICS]
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来源 :
CRYSTAL GROWTH & DESIGN
ISSN: 1528-7483
年份: 2017
期: 3
卷: 17
页码: 1008-1015
3 . 8 0 0
JCR@2022
ESI学科: CHEMISTRY;
ESI高被引阀值:127
中科院分区:2