Porous　Pt-doping　heterojunctions,　Pt-ZnO-Co3O4,　Pt-ZnS-CoS,　and　Pt-Zn3P2-CoP　were　fabricated　by　firstly　the　oxidation,　sulfurization,　and　phosphorization　of　ZnCo-zeolitic-imidazolate-framework　9ZnCo-ZIF)　and　then　the　doping　of　Pt　nanoparticles.　They　exhibit　excellent　photocatalytic　activity　towards　hydrogen　generation　from　water　splitting.　These　bimetallic　metal-organic-framework　9MOF)　derivatives　maintain　the　porous　framework　skeleton　of　ZnCo-ZIF　precursor,　there　by　significantly　enhancing　the　light　utilization　and　simultaneously　affording　abundant　exposed　catalytic　active　sites.　Most　importantly,　suitable　band　matching　and　strong　electron　coupling　in　these　heterojunctions　are　achieved　by　using　the　bimetallic　MOF　template,　which　facilitate　the　efficient　electron-hole　separation　and　transportation.　In　addition,　Pt　nanoparticles　distributed　on　the　porous　heterojunctions　as　electron　traps　can　offer　rich　redox　active　sites　for　the　hydrogen　generation.　Correspondingly,　the　hydrogen　generation　rate　of　Pt-ZnO-Co3O4,　Pt-ZnS-CoS,　and　Pt-Zn3P2-CoP　was　up　to　similar　to　7.80,　similar　to　8.21,　and　similar　to　9.15　mmol　h(-1)　g(-1)　,　respectively,　higher　than　those　of　respective　ZIF-8　or　ZIF-67-based　derivatives.　This　work　thus　provides　a　new　approach　that　using　bimetallic　MOF　as　template　directs　the　fabrication　of　noble-metal　doping　heterojunctions　to　simultaneously　enhance　light　absorption　utilization,　electro-hole　separation,　and　transport,　therefore　promoting　surface　water　oxidation　reaction　for　efficient　water　splitting.