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作者:

Liu, Lisha (Liu, Lisha.) | Song, Yong (Song, Yong.) | Fu, Zhidan (Fu, Zhidan.) | Ye, Qing (Ye, Qing.) (学者:叶青) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Kang, Tianfang (Kang, Tianfang.) (学者:康天放) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

收录:

EI Scopus SCIE

摘要:

The cryptomelane-type manganese oxide octahedral molecular sieve (OMS-2)-supported Pd (0.5 wt% Pd/OMS-2-DP, 0.5 wt% Pd/OMS-2-PI, and 0.5 wt% Pd/OMS-2-EX) catalysts were prepared by the deposition-precipitation, pre-incorporation, and ion-exchanging strategies, respectively. It is shown that the preparation method exerted an important effect on the physicochemical property of the sample. Among the OMS-2-supported Pd catalysts, 0.5 wt% Pd/OMS-2-DP possessed the highest surface (Mn2+ + Mn3+)/Mn4+ atomic ratio and the highest surface Pd loading and acid sites. The 0.5 wt% Pd/OMS-2 catalysts outperformed the Pd-free counterpart, among which 0.5 wt% Pd/OMS-2-DP presented the best catalytic activity (T-50% and T-90% were 25 and 55 degrees C for CO oxidation, 240 and 285 degrees C for toluene oxidation, and 160 and 200 degrees C for ethyl acetate oxidation, respectively). We believe that the high Pd surface loading, high surface atomic ratio of (Mn2+ + Mn3+)/Mn4+, and good low-temperature reducibility, good oxygen mobility, and high acidity were responsible for the excellent performance of the 0.5 wt% Pd/OMS-2-DP catalyst. (C) 2016 Elsevier B.V. All rights reserved.

关键词:

Carbon monoxide oxidation Cryptomelane-type manganese oxide octahedral molecular sieve Oxygen mobility Supported Pd catalyst Volatile organic compound combustion

作者机构:

  • [ 1 ] [Liu, Lisha]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Song, Yong]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Fu, Zhidan]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Ye, Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Cheng, Shuiyuan]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Kang, Tianfang]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing Key Lab Green Catalysis & Separat, Dept Chem & Chem Engn,Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青 戴洪兴

    [Ye, Qing]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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来源 :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

年份: 2017

卷: 396

页码: 599-608

6 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:169

中科院分区:1

被引次数:

WoS核心集被引频次: 59

SCOPUS被引频次: 62

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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