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作者:

Yuan, Y. (Yuan, Y..) | Wu, Y. (Wu, Y..) | Tong, X. (Tong, X..) | Zhang, H. (Zhang, H..) | Wang, H. (Wang, H..) | Liu, X. J. (Liu, X. J..) | Ma, L. (Ma, L..) | Suo, H. L. (Suo, H. L..) (学者:索红莉) | Lu, Z. P. (Lu, Z. P..)

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EI Scopus SCIE

摘要:

In this paper, we report the development of rare-earth high-entropy alloys (RE-HEA) with multiple principle elements randomly distributed on a single hexagonal close-packed (HCP) lattice. Our work demonstrated that it is the entropy, rather than other atomic factors such as enthalpy, atomic size and electronegativity, that dictates phase formation in the current rare-earth alloy system. The high configuration entropy stabilized the crystalline structure from phase transformation during cooling, whereas a second-order magnetic phase transition occurred at its Neel temperature. The quinary RE-HEA exhibited a small magnetic hysteresis and the largest refrigerant capacity (about 627 J kg(-1) at the 5 T magnetic field) reported to date, along with respectable mechanical properties. Our analysis indicates that the strong chemical disorder resulted from the high configuration entropy makes magnetic ordering in the HEA difficult, thus giving rise to a sluggish magnetic phase transition and enhanced magneto caloric effect. Our findings evidenced that RE-HEAs have great potential to be used as magnetic refrigerants and the alloy-design concept of HEAs can be employed to develop novel high-performance magnetocaloric materials. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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作者机构:

  • [ 1 ] [Yuan, Y.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
  • [ 2 ] [Wu, Y.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
  • [ 3 ] [Wang, H.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
  • [ 4 ] [Liu, X. J.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
  • [ 5 ] [Lu, Z. P.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
  • [ 6 ] [Tong, X.]Oak Ridge Natl Lab, Instrument & Source Div, Oak Ridge, TN 37831 USA
  • [ 7 ] [Tong, X.]Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA
  • [ 8 ] [Zhang, H.]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 9 ] [Ma, L.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 10 ] [Suo, H. L.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Wu, Y.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China;;[Lu, Z. P.]Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China

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来源 :

ACTA MATERIALIA

ISSN: 1359-6454

年份: 2017

卷: 125

页码: 481-489

9 . 4 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:287

中科院分区:1

被引次数:

WoS核心集被引频次: 190

SCOPUS被引频次: 194

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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