Electrochemical regioselective azidoiodination of alkenes - 文章详情页

作者：

Yan, Wei-qing (Yan, Wei-qing.) | Lin, Meng-ying (Lin, Meng-ying.) | Little, R. Daniel (Little, R. Daniel.) | Zeng, Cheng-Chu (Zeng, Cheng-Chu.) (学者：曾程初)

收录：

Scopus SCIE

摘要：

An　efficient　electrochemical　approach　to　the　vicinal　iodoazides　has　been　developed　through　constant　current　electrolysis　of　alkenes　with　NaN3　and　Nal　in　methanol.　The　reaction　is　proposed　to　proceed　via　a　cyclic　iodonium　intermediate　and　thereby　gives　Markovnikov　addition　products　exclusively.　(C)　2016　Elsevier　Ltd.　All　rights　reserved.

关键词：

Markovnikov addition Cyclic iodonium intermediate Azidoiodination of alkenes Electrosynthesis

作者机构：

[ 1 ] [Yan, Wei-qing]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China
[ 2 ] [Lin, Meng-ying]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China
[ 3 ] [Zeng, Cheng-Chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China
[ 4 ] [Little, R. Daniel]Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

通讯作者信息：

曾程初
[Zeng, Cheng-Chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China

电子邮件地址：

zengcc@bjut.edu.cn

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