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作者:

Xi, Xiaoli (Xi, Xiaoli.) (学者:席晓丽) | Song, Shanshan (Song, Shanshan.) | Nie, Zuoren (Nie, Zuoren.) (学者:聂祚仁) | Ma, Liwen (Ma, Liwen.)

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Scopus SCIE

摘要:

This paper reports the electrodeposition of Pd in the room-temperature ionic liquid 1-ethyl-3methylimidazolium trifluoroacetate ([emim] TA). The electrochemical behavior of PdC(l)2 in [emim] TA was investigated using cyclic voltammetry. Cyclic voltammograms were recorded at various scan rates and temperatures and showed that the reduction of Pd was irreversible. The diffusion coefficient of PdCl2 in [emim] TA increased with increasing temperature and the diffusion activation energy was determined to be 43.66 KJ mol-1. The optimum parameters of Pd electrodeposition in [emim] TA were determined through single-factor experiments. The surface morphology of the deposits was analyzed via scanning electron microscopy and the crystal structure of metallic Pd was confirmed through X-ray diffraction.

关键词:

Electrochemical behavior Electrodeposition [emim] TA Palladium

作者机构:

  • [ 1 ] [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Song, Shanshan]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Liwen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 席晓丽

    [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

ISSN: 1452-3981

年份: 2017

期: 2

卷: 12

页码: 1130-1145

1 . 5 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:127

中科院分区:4

被引次数:

WoS核心集被引频次: 3

SCOPUS被引频次: 3

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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