收录:
摘要:
This paper reports the electrodeposition of Pd in the room-temperature ionic liquid 1-ethyl-3methylimidazolium trifluoroacetate ([emim] TA). The electrochemical behavior of PdC(l)2 in [emim] TA was investigated using cyclic voltammetry. Cyclic voltammograms were recorded at various scan rates and temperatures and showed that the reduction of Pd was irreversible. The diffusion coefficient of PdCl2 in [emim] TA increased with increasing temperature and the diffusion activation energy was determined to be 43.66 KJ mol-1. The optimum parameters of Pd electrodeposition in [emim] TA were determined through single-factor experiments. The surface morphology of the deposits was analyzed via scanning electron microscopy and the crystal structure of metallic Pd was confirmed through X-ray diffraction.
关键词:
通讯作者信息:
电子邮件地址:
来源 :
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
ISSN: 1452-3981
年份: 2017
期: 2
卷: 12
页码: 1130-1145
1 . 5 0 0
JCR@2022
ESI学科: CHEMISTRY;
ESI高被引阀值:212
中科院分区:4