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作者:

Sun, Boxue (Sun, Boxue.) | Liu, Yu (Liu, Yu.) | Nie, Zuoren (Nie, Zuoren.) (学者:聂祚仁) | Gao, Feng (Gao, Feng.) | Wang, Zhihong (Wang, Zhihong.) | Gong, Xianzheng (Gong, Xianzheng.)

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摘要:

Purpose The objectives of this study were to establish an allocation model for the energy consumption of pyro-metallurgical system based on the physical relationship between the input and output, apply the established model to nickel production in China and compare the difference between the allocation results derived from the established model and the traditional models. Methods The basic methodological idea of this study is that the energy input of a multi-output pyro-metallurgical process should be allocated according to how the energy input is consumed in the process. The energy consumption of pyro-metallurgical system was decomposed into different categories (e.g. energy absorption of chemical reaction and energy loss), and these categories were classified into two groups, i.e. the categories of energy consumption dependent on the product ratio (PRDE) and the categories of energy consumption independent on the product ratio (PRIE); then, the allocation basis for each category of energy consumption was determined through the physical relationship between the energy input and metal output. The allocation for the energy consumption of nickel production in China was carried out; the system boundary includes two sub-systems (i.e. Ni-Cu coproduction system and Ni refining system), and the energy consumption of the coproduction system should be allocated; the basic data required by the allocation model and the compilation of LCI were mainly obtained from literature. Results and discussion The energy consumption of the processes of mining, drying, converting and floating-grinding belongs to PRIE following the principle of mass-based allocation, and the corresponding allocation factors are 64, 64, 69 and 69 %, respectively. The categories of energy consumption involved in the smelting process (the key process for demonstrating the allocation model) include both PRIE and PRDE, and the aggregated allocation factor was calculated as 56 %. The allocation result derived from the established model is lower than the results derived from the mass-based model and the market value-based model, because that, through the desulphurization reactions that occurred in the smelting process, the chemical states of copper and nickel are transformed from copper pyrite (CuFeS2) and nicopyrite ((Fe, Ni)(9)S-8) into cuprous sulphide (Cu2S) and nickel sulphide (Ni3S2), and copper compound releases more sulphur atoms than nickel compound. When analyzing a single pyro-metallurgical process, the result of allocation is sensitive to basis selection; however, when comparing two or more pyro-metallurgical processes, the comparison result of allocation is relatively insensitive to basis selection. Conclusions The energy input of pyro-metallurgical system is consumed in different physical-chemical ways; the decomposition of energy consumption is significant for choosing allocation bases; the basis of mass can only be used for the allocation of PRIE, and choosing the same allocation basis for different cases without a systematic analysis will be inappropriate. The requirement of some nontraditional extra inventory data is the major limitation of the established model. This study mainly focused on how nickel production system consumes the energy input, and the energy consumption patterns of other production systems should be taken into account in future studies.

关键词:

Allocation China Life cycle assessment Nickel Pyro-metallurgy

作者机构:

  • [ 1 ] [Sun, Boxue]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Yu]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China
  • [ 3 ] [Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China
  • [ 4 ] [Gao, Feng]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Zhihong]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China
  • [ 6 ] [Gong, Xianzheng]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China

通讯作者信息:

  • [Sun, Boxue]Beijing Univ Technol, Coll Mat Sci & Engn, Ctr Natl Mat Life Cycle Assessment, Beijing 100124, Peoples R China

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来源 :

INTERNATIONAL JOURNAL OF LIFE CYCLE ASSESSMENT

ISSN: 0948-3349

年份: 2017

期: 2

卷: 22

页码: 199-212

4 . 8 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:92

中科院分区:2

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 1

ESI高被引论文在榜: 0 展开所有

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