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Controlling phase transition in functional materials at nano scale is not only of broad scientific interest but also important for practical applications in the fields of renewable energy, information storage, transducer, sensor, and so forth. As a model functional material, vanadium dioxide (VO2) has its metal insulator transition (MIT) usually at a sharp temperature around 68 degrees C. Here, we report a focused electron beam can directly lower down the transition temperature of a nanoarea to room temperature without prepatterning the VO2. This novel process is called radiolysis-assisted MIT (R-MIT). The electron beam irradiation fabricates a unique gradual MIT zone to several times of the beam size in which the temperature-dependent phase transition is achieved in an extended temperature range. The gradual transformation zone offers to precisely control the ratio of metal/insulator phases. This direct electron writing technique can open up an opportunity to precisely engineer nanodomains of diversified electronic properties in functional material-based devices.
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NANO LETTERS
ISSN: 1530-6984
年份: 2017
期: 2
卷: 17
页码: 851-855
1 0 . 8 0 0
JCR@2022
ESI学科: PHYSICS;
ESI高被引阀值:94
中科院分区:1