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作者:

Zhang, Zhenhua (Zhang, Zhenhua.) | Guo, Hua (Guo, Hua.) | Ding, Wenqiang (Ding, Wenqiang.) | Zhang, Bin (Zhang, Bin.) | Lu, Yue (Lu, Yue.) (学者:卢岳) | Ke, Xiaoxing (Ke, Xiaoxing.) | Liu, Weiwei (Liu, Weiwei.) | Chen, Furong (Chen, Furong.) | Sui, Manling (Sui, Manling.) (学者:隋曼龄)

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摘要:

Controlling phase transition in functional materials at nano scale is not only of broad scientific interest but also important for practical applications in the fields of renewable energy, information storage, transducer, sensor, and so forth. As a model functional material, vanadium dioxide (VO2) has its metal insulator transition (MIT) usually at a sharp temperature around 68 degrees C. Here, we report a focused electron beam can directly lower down the transition temperature of a nanoarea to room temperature without prepatterning the VO2. This novel process is called radiolysis-assisted MIT (R-MIT). The electron beam irradiation fabricates a unique gradual MIT zone to several times of the beam size in which the temperature-dependent phase transition is achieved in an extended temperature range. The gradual transformation zone offers to precisely control the ratio of metal/insulator phases. This direct electron writing technique can open up an opportunity to precisely engineer nanodomains of diversified electronic properties in functional material-based devices.

关键词:

domain wall metal-insulator transition (MIT) oxygen vacancy radiolysis transition temperature Vanadium dioxide (VO2)

作者机构:

  • [ 1 ] [Zhang, Zhenhua]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Ding, Wenqiang]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Bin]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Lu, Yue]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Ke, Xiaoxing]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Sui, Manling]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Guo, Hua]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 8 ] [Chen, Furong]Natl Tsing Hua Univ, Dept Engn & Syst Sci, Hsinchu 300, Taiwan
  • [ 9 ] [Liu, Weiwei]Beijing Computat Sci Res Ctr, Beijing 100084, Peoples R China

通讯作者信息:

  • 隋曼龄

    [Sui, Manling]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China;;[Chen, Furong]Natl Tsing Hua Univ, Dept Engn & Syst Sci, Hsinchu 300, Taiwan

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来源 :

NANO LETTERS

ISSN: 1530-6984

年份: 2017

期: 2

卷: 17

页码: 851-855

1 0 . 8 0 0

JCR@2022

ESI学科: PHYSICS;

ESI高被引阀值:94

中科院分区:1

被引次数:

WoS核心集被引频次: 37

SCOPUS被引频次: 34

ESI高被引论文在榜: 0 展开所有

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